Bromoacetic acid
- BROMOACETIC ACID
- 2-Bromoacetic acid
- 79-08-3
- Acetic acid, bromo-
- Monobromoacetic acid
- Create:2005-03-26
- Modify:2025-01-18
- bromoacetate
- bromoacetic acid
- monobromoacetate
- BROMOACETIC ACID
- 2-Bromoacetic acid
- 79-08-3
- Acetic acid, bromo-
- Monobromoacetic acid
- Bromoethanoic acid
- To NTU
- Bromoacetate ion
- Acide bromacetique
- 2-Bromoacetyl Group
- Acetic acid, 2-bromo-
- 2-bromoethanoic acid
- Bromo-acetic acid
- Monobromessigsaeure
- Kyselina bromoctova
- .alpha.-Bromoacetic acid
- NSC 141
- Bromoacetic acid, solid
- MFCD00002678
- CHEMBL60851
- DTXSID7021495
- NSC-141
- 2B3HS32431
- alpha-Bromoacetic acid
- Caswell No. 112A
- 2-Bromoaceticacid
- Acide bromacetique [French]
- Kyselina bromoctova [Czech]
- Monobromessigsaeure [German]
- CCRIS 7886
- EINECS 201-175-8
- UN1938
- EPA Pesticide Chemical Code 008702
- BRN 0506167
- bromacetic acid
- AI3-15301
- UNII-2B3HS32431
- HSDB 7627
- bromo acetic acid
- monobromacetic acid
- Carboxymethyl bromide
- 2-bromo acetic acid
- 2-bromo-acetic acid
- CH2BrCOOH
- UN 1938
- 2-bromanylethanoic acid
- 44 - Haloacetic Acids
- .alpha.-Bromoethanoic acid
- WLN: QV1E
- EC 201-175-8
- SCHEMBL23032
- 4-02-00-00526 (Beilstein Handbook Reference)
- BROMOACETIC ACID [MI]
- BROMOACETIC ACID, 2-
- DTXCID601495
- NSC141
- BROMOACETIC ACID [HSDB]
- STR00860
- Tox21_200657
- BDBM50119693
- Bromoacetic acid, analytical standard
- LMFA01090074
- STL481895
- AKOS000118919
- Bromoacetic acid, reagent grade, 97%
- DB02198
- CAS-79-08-3
- NCGC00091467-01
- NCGC00091467-02
- NCGC00258211-01
- BP-20544
- Bromoacetic acid, purum, >=98.0% (T)
- 1ST70014-1000Q
- Bromoacetic acid, ReagentPlus(R), >=99%
- B0531
- NS00010208
- Bromoacetic acid, ReagentPlus(R), >=99.0%
- EN300-19170
- Bromoacetic acid Solution in MTBE, 1000ug/mL
- G77237
- Bromoacetic acid, solid [UN1938] [Corrosive]
- A839576
- Q421323
- J-519938
- F2191-0223
- InChI=1/C2H3BrO2/c3-1-2(4)5/h1H2,(H,4,5
- Z104473018
- Bromoacetic acid 1000 microg/mL in Methyl-tert-butyl ether
- Boiling point
- Density
- Diamagnetic susceptibility
- Heat of sublimation
- Magnetic susceptibility
- Molecular structure
- Nuclear quadrupole coupling
- Nuclear quadrupole moment
- Nuclear quadrupole resonance spectroscopy
- Optical coefficient
- Quadrupole coupling
- Refractive index
- Rotational excitation cross section
- Surface tension
- Vapor pressure
- Vibrational mode frequency
- Viscosity
H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]
H311 (61.2%): Toxic in contact with skin [Danger Acute toxicity, dermal]
H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]
H317 (95.5%): May cause an allergic skin reaction [Warning Sensitization, Skin]
H331 (100%): Toxic if inhaled [Danger Acute toxicity, inhalation]
H400 (100%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]
P260, P261, P262, P264, P270, P271, P272, P273, P280, P301+P316, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P330, P333+P317, P361+P364, P362+P364, P363, P391, P403+P233, P405, and P501
(The corresponding statement to each P-code can be found at the GHS Classification page.)
Aggregated GHS information provided per 134 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown.
Acute Tox. 3 (100%)
Acute Tox. 3 (61.2%)
Skin Corr. 1A (100%)
Skin Sens. 1 (95.5%)
Acute Tox. 3 (100%)
Aquatic Acute 1 (100%)
Acute toxicity - category 3
Acute toxicity - category 3
Acute toxicity - category 3
Skin corrosion - category 1A
Hazardous to the aquatic environment (acute) - category 1
Skin sensitisation - category 1
Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
TOXIC and/or CORROSIVE; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Contact with molten substance may cause severe burns to skin and eyes. Reaction with water or moist air may release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental contamination. (ERG, 2024)
· TOXIC and/or CORROSIVE; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death.
· Contact with molten substance may cause severe burns to skin and eyes.
· Reaction with water or moist air may release toxic, corrosive or flammable gases.
· Reaction with water may generate much heat that will increase the concentration of fumes in the air.
· Fire will produce irritating, corrosive and/or toxic gases.
· Runoff from fire control or dilution water may be corrosive and/or toxic and cause environmental contamination.
Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
Combustible material: may burn but does not ignite readily. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas (sewers, basements, tanks, etc.). Vapors may travel to source of ignition and flash back. Corrosives in contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water. (ERG, 2024)
· Combustible material: may burn but does not ignite readily.
· Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff.
· When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards.
· Most vapors are heavier than air. They will spread along the ground and collect in low or confined areas (sewers, basements, tanks, etc.).
· Vapors may travel to source of ignition and flash back.
· Corrosives in contact with metals may evolve flammable hydrogen gas.
· Containers may explode when heated or if contaminated with water.
Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
Refer to the "General First Aid" section. Specific First Aid: For corrosives, in case of contact, immediately flush skin or eyes with running water for at least 30 minutes. Additional flushing may be required. Removal of solidified molten material from skin requires medical assistance. (ERG, 2024)
General First Aid:
· Call 911 or emergency medical service.
· Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and avoid contamination.
· Move victim to fresh air if it can be done safely.
· Administer oxygen if breathing is difficult.
· If victim is not breathing:
-- DO NOT perform mouth-to-mouth resuscitation; the victim may have ingestedor inhaled the substance.
-- If equipped and pulse detected, wash face and mouth, then give artificial respiration using a proper respiratory medical device (bag-valve mask, pocket mask equipped with a one-way valve or other device).
-- If no pulse detected or no respiratory medical device available, provide continuouscompressions. Conduct a pulse check every two minutes or monitor for any signs of spontaneous respirations.
· Remove and isolate contaminated clothing and shoes.
· For minor skin contact, avoid spreading material on unaffected skin.
· In case of contact with substance, remove immediately by flushing skin or eyes with running water for at least 20 minutes.
· For severe burns, immediate medical attention is required.
· Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed.
· Keep victim calm and warm.
· Keep victim under observation.
· For further assistance, contact your local Poison Control Center.
· Note: Basic Life Support (BLS) and Advanced Life Support (ALS) should be done by trained professionals.
Specific First Aid:
· For corrosives, in case of contact, immediately flush skin or eyes with running water for at least 30 minutes. Additional flushing may be required.
· Removal of solidified molten material from skin requires medical assistance.
In Canada, an Emergency Response Assistance Plan (ERAP) may be required for this product. Please consult the shipping paper and/or the "ERAP" section.
Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
Note: Most foams will react with the material and release corrosive/toxic gases. CAUTION: For Acetyl bromide (UN1716), use CO2 or dry chemical only.
SMALL FIRE: CO2, dry chemical, dry sand, alcohol-resistant foam.
LARGE FIRE: Water spray, fog or alcohol-resistant foam. FOR CHLOROSILANES, DO NOT USE WATER; use alcohol-resistant foam. If it can be done safely, move undamaged containers away from the area around the fire. Avoid aiming straight or solid streams directly onto the product.
FIRE INVOLVING TANKS, RAIL TANK CARS OR HIGHWAY TANKS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks in direct contact with flames. (ERG, 2024)
· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
· Keep unauthorized personnel away.
· Stay upwind, uphill and/or upstream.
· Ventilate closed spaces before entering, but only if properly trained and equipped.
· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.
· All equipment used when handling the product must be grounded.
· Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
· Stop leak if you can do it without risk.
· A vapor-suppressing foam may be used to reduce vapors.
· FOR CHLOROSILANES, use alcohol-resistant foam to reduce vapors.
· DO NOT GET WATER on spilled substance or inside containers.
· Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material.
· Prevent entry into waterways, sewers, basements or confined areas.
Small Spill
· Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain.
· Use clean, non-sparking tools to collect material and place it into loosely covered plastic containers for later disposal.
Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.
FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)
Immediate precautionary measure
· Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
Spill
· For highlighted materials: see Table 1 - Initial Isolation and Protective Action Distances.
· For non-highlighted materials: increase the immediate precautionary measure distance, in the downwind direction, as necessary.
Fire
· If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.
Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area. All equipment used when handling the product must be grounded. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. A vapor-suppressing foam may be used to reduce vapors. FOR CHLOROSILANES, use alcohol-resistant foam to reduce vapors. DO NOT GET WATER on spilled substance or inside containers. Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. Prevent entry into waterways, sewers, basements or confined areas.
SMALL SPILL: Cover with DRY earth, DRY sand or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain. Use clean, non-sparking tools to collect material and place it into loosely covered plastic containers for later disposal. (ERG, 2024)
· Wear positive pressure self-contained breathing apparatus (SCBA).
· Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE.
· Structural firefighters' protective clothing provides thermal protection but only limited chemical protection.
· Note: Most foams will react with the material and release corrosive/toxic gases.
CAUTION: For Acetyl bromide (UN1716), use CO2 or dry chemical only.
Small Fire
· CO2, dry chemical, dry sand, alcohol-resistant foam.
Large Fire
· Water spray, fog or alcohol-resistant foam.
· FOR CHLOROSILANES, DO NOT USE WATER; use alcohol-resistant foam.
· If it can be done safely, move undamaged containers away from the area around the fire.
· Avoid aiming straight or solid streams directly onto the product.
Fire Involving Tanks, Rail Tank Cars or Highway Tanks
· Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles.
· Do not get water inside containers.
· Cool containers with flooding quantities of water until well after fire is out.
· Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
· ALWAYS stay away from tanks in direct contact with flames.
Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE. Structural firefighters' protective clothing provides thermal protection but only limited chemical protection. (ERG, 2024)
Acids, Carboxylic
Halogenated Organic Compounds
Dermatotoxin - Skin burns.
Lacrimator (Lachrymator) - A substance that irritates the eyes and induces the flow of tears.
Skin Sensitizer - An agent that can induce an allergic reaction in the skin.
Patents are available for this chemical structure:
https://patentscope.wipo.int/search/en/result.jsf?inchikey=KDPAWGWELVVRCH-UHFFFAOYSA-N
Patents are available for this chemical structure:
https://patentscope.wipo.int/search/en/result.jsf?inchikey=HASIEPWTYCXUKM-UHFFFAOYSA-N
- Australian Industrial Chemicals Introduction Scheme (AICIS)Acetic acid, bromo-https://services.industrialchemicals.gov.au/search-inventory/
- CAMEO ChemicalsLICENSECAMEO Chemicals and all other CAMEO products are available at no charge to those organizations and individuals (recipients) responsible for the safe handling of chemicals. However, some of the chemical data itself is subject to the copyright restrictions of the companies or organizations that provided the data.https://cameochemicals.noaa.gov/help/reference/terms_and_conditions.htm?d_f=falseBROMOACETIC ACIDhttps://cameochemicals.noaa.gov/chemical/261BROMOACETIC ACID, SOLUTIONhttps://cameochemicals.noaa.gov/chemical/262CAMEO Chemical Reactivity Classificationhttps://cameochemicals.noaa.gov/browse/react
- CAS Common ChemistryLICENSEThe data from CAS Common Chemistry is provided under a CC-BY-NC 4.0 license, unless otherwise stated.https://creativecommons.org/licenses/by-nc/4.0/Bromoacetic acidhttps://commonchemistry.cas.org/detail?cas_rn=79-08-3
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- DrugBankLICENSECreative Common's Attribution-NonCommercial 4.0 International License (http://creativecommons.org/licenses/by-nc/4.0/legalcode)https://www.drugbank.ca/legal/terms_of_use2-Bromoacetyl Grouphttps://www.drugbank.ca/drugs/DB02198
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- EPA DSSToxBromoacetic acidhttps://comptox.epa.gov/dashboard/DTXSID7021495CompTox Chemicals Dashboard Chemical Listshttps://comptox.epa.gov/dashboard/chemical-lists/
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- Hazardous Substances Data Bank (HSDB)Bromoacetic acidhttps://pubchem.ncbi.nlm.nih.gov/source/hsdb/7627
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- NJDOH RTK Hazardous Substance Listbromoacetic acidhttp://nj.gov/health/eoh/rtkweb/documents/fs/2182.pdf
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- Emergency Response Guidebook (ERG)Bromoacetic acidhttps://pubchem.ncbi.nlm.nih.gov/erg/
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- IUPAC Digitized pKa Datasetacetic acid, bromo-https://github.com/IUPAC/Dissociation-Constants
- Therapeutic Target Database (TTD)2-Bromoacetyl Grouphttps://idrblab.net/ttd/data/drug/details/D05DOM
- EPA Regional Screening Levels for Chemical Contaminants at Superfund SitesBromoacetic acidhttps://epa-prgs.ornl.gov/cgi-bin/chemicals/csl_searchBromoacetic acidhttps://epa-prgs.ornl.gov/cgi-bin/chemicals/csl_search?tool=rml
- Hazardous Chemical Information System (HCIS), Safe Work Australia
- NITE-CMCBromoacetic acid - FY2009 (New/original classication)https://www.chem-info.nite.go.jp/chem/english/ghs/09-mhlw-0027e.htmlBromoacetic acid - FY2021 (Revised classification)https://www.chem-info.nite.go.jp/chem/english/ghs/21-mhlw-2054e.html
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- NMRShiftDB
- Japan Chemical Substance Dictionary (Nikkaji)
- LIPID MAPS2-bromoacetic acidhttps://lipidmaps.org/databases/lmsd/LMFA01090074Lipid Classificationhttps://www.lipidmaps.org/
- Metabolomics Workbench2-bromoacetic acidhttps://www.metabolomicsworkbench.org/data/StructureData.php?RegNo=1760
- Nature Synthesis
- NIST Mass Spectrometry Data CenterLICENSEData covered by the Standard Reference Data Act of 1968 as amended.https://www.nist.gov/srd/public-lawAcetic acid, bromo-http://www.nist.gov/srd/nist1a.cfm
- SpectraBaseBROMOACETIC ACIDhttps://spectrabase.com/spectrum/FEkdZSiVNJeACETIC ACID, BROMO-https://spectrabase.com/spectrum/6Agp5ZDPi3GBROMOACETIC ACIDhttps://spectrabase.com/spectrum/BIAnH2a65pbromoacetic acidhttps://spectrabase.com/spectrum/2JBiLeVB6VbBROMOACETIC ACIDhttps://spectrabase.com/spectrum/26rRx41lRVIAcetic acid, bromo-https://spectrabase.com/spectrum/4sRSVuWfYrzACETIC ACID, BROMO-,https://spectrabase.com/spectrum/693IdpBVoB5Acetic acid, bromo-https://spectrabase.com/spectrum/1ybzghv77yFAcetic acid, bromo-https://spectrabase.com/spectrum/9NH712PcR4fBromoacetic acidhttps://spectrabase.com/spectrum/Dxj16LQErGOBromoacetic acidhttps://spectrabase.com/spectrum/8dwBMGUL142Bromoacetic acidhttps://spectrabase.com/spectrum/6m6mXsCgQz5
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- Protein Data Bank in Europe (PDBe)
- RCSB Protein Data Bank (RCSB PDB)LICENSEData files contained in the PDB archive (ftp://ftp.wwpdb.org) are free of all copyright restrictions and made fully and freely available for both non-commercial and commercial use. Users of the data should attribute the original authors of that structural data.https://www.rcsb.org/pages/policies
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- Wikidatabromoacetic acidhttps://www.wikidata.org/wiki/Q421323
- Wikipedia3-Methylglutaconyl-CoAhttps://en.wikipedia.org/wiki/3-Methylglutaconyl-CoABromoacetic acidhttps://en.wikipedia.org/wiki/Bromoacetic_acid
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- MolGenieMolGenie Organic Chemistry Ontologyhttps://github.com/MolGenie/ontology/
- PATENTSCOPE (WIPO)SID 403384066https://pubchem.ncbi.nlm.nih.gov/substance/403384066SID 404296892https://pubchem.ncbi.nlm.nih.gov/substance/404296892