Bromobenzyl Cyanide
- Bromobenzyl cyanide
- 5798-79-8
- 2-bromo-2-phenylacetonitrile
- Bromo(phenyl)acetonitrile
- Camite
- Create:2005-03-27
- Modify:2025-01-25
19472-74-3
31938-07-5
16532-79-9
5798-79-8
- Bromobenzyl cyanide
- 5798-79-8
- 2-bromo-2-phenylacetonitrile
- Bromo(phenyl)acetonitrile
- Camite
- Brombenzyl cyanide
- Bromobenzylcyanide
- Bromobenzylnitrile
- alpha-Bromophenylacetonitrile
- alpha-Bromobenzeneacetonitrile
- ALPHA-BROMOBENZYL CYANIDE
- Acetonitrile, bromophenyl-
- bromo benzyl cyanide
- alpha-Brombenzylkyanid
- alpha-Brombenzylkyanid [Czech]
- HSDB 1982
- Acetic acid, bromophenyl-, nitrile
- EINECS 227-348-8
- UNII-7JP1R2F6C6
- BRN 1862309
- 7JP1R2F6C6
- ALPHA-BROMOBENZYL CYANID
- CHEMBL1085832
- DTXSID50871146
- 3-09-00-02278 (Beilstein Handbook Reference)
- .ALPHA.-BROMOBENZENEACETONITRILE
- .ALPHA.-BROMOBENZYL CYANIDE [MI]
- CA (Tear gas)
- alpha-Bromo-alpha-tolunitrile
- Benzeneacetonitrile, alpha-bromo-
- Benzeneacetonitrile, .alpha.-bromo-
- Brombenzylcyanid
- cyanobenzyl bromide
- Bromobenzyl cyanides
- alphaBrombenzylkyanid
- UN1694
- bromophenylacetonitrile
- alphaBromobenzyl cyanide
- alphaBromoalphatolunitrile
- Acetonitrile, bromophenyl
- alphaBromophenylacetonitrile
- alphaBromobenzeneacetonitrile
- .alpha.-Bromobenzyl cyanide
- SCHEMBL437646
- Benzeneacetonitrile, alphabromo
- DTXCID90818818
- Acetic acid, bromophenyl, nitrile
- BDBM50318515
- MFCD01672925
- AKOS005146417
- AS-30796
- DB-029546
- NS00047481
- A18929
- Q425589
- J-519942
- Z1198157485
H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]
H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
H319 (97.4%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]
H335 (100%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]
P261, P264, P264+P265, P270, P271, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501
(The corresponding statement to each P-code can be found at the GHS Classification page.)
Aggregated GHS information provided per 39 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown.
Acute Tox. 4 (100%)
Skin Irrit. 2 (100%)
Eye Irrit. 2 (97.4%)
STOT SE 3 (100%)
For information on chemical warfare tear gas agents see the ERG Criminal or Terrorist Use of CBR Agents. (ERG, 2024)
Excerpt from ERG Guide 159 [Substances (Irritating)]:
Inhalation of vapors or dust is extremely irritating. May cause burning of eyes and lachrymation (flow of tears). May cause coughing, difficult breathing and nausea. Brief exposure effects last only a few minutes. Exposure in an enclosed area may be very harmful. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause environmental contamination. (ERG, 2024)
· Inhalation of vapors or dust is extremely irritating.
· May cause burning of eyes and lachrymation (flow of tears).
· May cause coughing, difficult breathing and nausea.
· Brief exposure effects last only a few minutes.
· Exposure in an enclosed area may be very harmful.
· Fire will produce irritating, corrosive and/or toxic gases.
· Runoff from fire control or dilution water may cause environmental contamination.
For information on chemical warfare tear gas agents see the ERG Criminal or Terrorist Use of CBR Agents. (ERG, 2024)
Excerpt from ERG Guide 159 [Substances (Irritating)]:
Some of these materials may burn, but none ignite readily. Containers may explode when heated. (ERG, 2024)
· Some of these materials may burn, but none ignite readily.
· Containers may explode when heated.
For information on chemical warfare tear gas agents see the ERG Criminal or Terrorist Use of CBR Agents. (ERG, 2024)
Excerpt from ERG Guide 159 [Substances (Irritating)]:
Refer to the "General First Aid" section. (ERG, 2024)
General First Aid:
· Call 911 or emergency medical service.
· Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and avoid contamination.
· Move victim to fresh air if it can be done safely.
· Administer oxygen if breathing is difficult.
· If victim is not breathing:
-- DO NOT perform mouth-to-mouth resuscitation; the victim may have ingestedor inhaled the substance.
-- If equipped and pulse detected, wash face and mouth, then give artificial respiration using a proper respiratory medical device (bag-valve mask, pocket mask equipped with a one-way valve or other device).
-- If no pulse detected or no respiratory medical device available, provide continuouscompressions. Conduct a pulse check every two minutes or monitor for any signs of spontaneous respirations.
· Remove and isolate contaminated clothing and shoes.
· For minor skin contact, avoid spreading material on unaffected skin.
· In case of contact with substance, remove immediately by flushing skin or eyes with running water for at least 20 minutes.
· For severe burns, immediate medical attention is required.
· Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed.
· Keep victim calm and warm.
· Keep victim under observation.
· For further assistance, contact your local Poison Control Center.
· Note: Basic Life Support (BLS) and Advanced Life Support (ALS) should be done by trained professionals.
In Canada, an Emergency Response Assistance Plan (ERAP) may be required for this product. Please consult the shipping paper and/or the "ERAP" section.
For information on chemical warfare tear gas agents see the ERG Criminal or Terrorist Use of CBR Agents. (ERG, 2024)
Excerpt from ERG Guide 159 [Substances (Irritating)]:
SMALL FIRE: Dry chemical, CO2, water spray or regular foam.
LARGE FIRE: Water spray, fog or regular foam. If it can be done safely, move undamaged containers away from the area around the fire. Dike runoff from fire control for later disposal.
FIRE INVOLVING TANKS, RAIL TANK CARS OR HIGHWAY TANKS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks in direct contact with flames. For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn. (ERG, 2024)
· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
· Keep unauthorized personnel away.
· Stay upwind, uphill and/or upstream.
· Ventilate closed spaces before entering, but only if properly trained and equipped.
· Do not touch or walk through spilled material.
· Stop leak if you can do it without risk.
Small Spill
· Pick up with sand or other non-combustible absorbent material and place into containers for later disposal.
Large Spill
· Dike far ahead of liquid spill for later disposal.
· Prevent entry into waterways, sewers, basements or confined areas.
For initial isolation and protective action distances for chemical warfare tear gas agents see the Chemical Warfare Agents table in the ERG Criminal or Terrorist Use of CBR Agents. (ERG, 2024)
Excerpt from ERG Guide 159 [Substances (Irritating)]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
LARGE SPILL: Consider initial downwind evacuation for at least 100 meters (330 feet).
FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)
Immediate precautionary measure
· Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
Large Spill
· Consider initial downwind evacuation for at least 100 meters (330 feet).
Fire
· If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.
For information on chemical warfare tear gas agents see the ERG Criminal or Terrorist Use of CBR Agents. (ERG, 2024)
Excerpt from ERG Guide 159 [Substances (Irritating)]:
Do not touch or walk through spilled material. Stop leak if you can do it without risk.
SMALL SPILL: Pick up with sand or other non-combustible absorbent material and place into containers for later disposal.
LARGE SPILL: Dike far ahead of liquid spill for later disposal. Prevent entry into waterways, sewers, basements or confined areas. (ERG, 2024)
· Wear positive pressure self-contained breathing apparatus (SCBA).
· Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE.
· Structural firefighters' protective clothing provides thermal protection but only limited chemical protection.
Small Fire
· Dry chemical, CO2, water spray or regular foam.
Large Fire
· Water spray, fog or regular foam.
· If it can be done safely, move undamaged containers away from the area around the fire.
· Dike runoff from fire control for later disposal.
Fire Involving Tanks, Rail Tank Cars or Highway Tanks
· Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles.
· Do not get water inside containers.
· Cool containers with flooding quantities of water until well after fire is out.
· Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
· ALWAYS stay away from tanks in direct contact with flames.
· For massive fire, use unmanned master stream devices or monitor nozzles; if this is impossible, withdraw from area and let fire burn.
For information on chemical warfare tear gas agents see the ERG Criminal or Terrorist Use of CBR Agents. (ERG, 2024)
Excerpt from ERG Guide 159 [Substances (Irritating)]:
Wear positive pressure self-contained breathing apparatus (SCBA). Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE. Structural firefighters' protective clothing provides thermal protection but only limited chemical protection. (ERG, 2024)
Nitriles
Aryl Halides
Patents are available for this chemical structure:
https://patentscope.wipo.int/search/en/result.jsf?inchikey=XUHFBOUSHUEAQZ-UHFFFAOYSA-N
- CAMEO ChemicalsLICENSECAMEO Chemicals and all other CAMEO products are available at no charge to those organizations and individuals (recipients) responsible for the safe handling of chemicals. However, some of the chemical data itself is subject to the copyright restrictions of the companies or organizations that provided the data.https://cameochemicals.noaa.gov/help/reference/terms_and_conditions.htm?d_f=falseBROMOBENZYL CYANIDEShttps://cameochemicals.noaa.gov/chemical/2651CAMEO Chemical Reactivity Classificationhttps://cameochemicals.noaa.gov/browse/react
- CAS Common ChemistryLICENSEThe data from CAS Common Chemistry is provided under a CC-BY-NC 4.0 license, unless otherwise stated.https://creativecommons.org/licenses/by-nc/4.0/α-Bromobenzeneacetonitrilehttps://commonchemistry.cas.org/detail?cas_rn=5798-79-8
- ChemIDplusalpha-Bromobenzyl cyanidehttps://pubchem.ncbi.nlm.nih.gov/substance/?source=chemidplus&sourceid=0005798798ChemIDplus Chemical Information Classificationhttps://pubchem.ncbi.nlm.nih.gov/source/ChemIDplus
- EPA DSSToxBromo(phenyl)acetonitrilehttps://comptox.epa.gov/dashboard/DTXSID50871146CompTox Chemicals Dashboard Chemical Listshttps://comptox.epa.gov/dashboard/chemical-lists/
- European Chemicals Agency (ECHA)LICENSEUse of the information, documents and data from the ECHA website is subject to the terms and conditions of this Legal Notice, and subject to other binding limitations provided for under applicable law, the information, documents and data made available on the ECHA website may be reproduced, distributed and/or used, totally or in part, for non-commercial purposes provided that ECHA is acknowledged as the source: "Source: European Chemicals Agency, http://echa.europa.eu/". Such acknowledgement must be included in each copy of the material. ECHA permits and encourages organisations and individuals to create links to the ECHA website under the following cumulative conditions: Links can only be made to webpages that provide a link to the Legal Notice page.https://echa.europa.eu/web/guest/legal-noticeBromo(phenyl)acetonitrilehttps://echa.europa.eu/substance-information/-/substanceinfo/100.024.863Bromo(phenyl)acetonitrile (EC: 227-348-8)https://echa.europa.eu/information-on-chemicals/cl-inventory-database/-/discli/details/108442
- FDA Global Substance Registration System (GSRS)LICENSEUnless otherwise noted, the contents of the FDA website (www.fda.gov), both text and graphics, are not copyrighted. They are in the public domain and may be republished, reprinted and otherwise used freely by anyone without the need to obtain permission from FDA. Credit to the U.S. Food and Drug Administration as the source is appreciated but not required.https://www.fda.gov/about-fda/about-website/website-policies#linkingBROMOBENZYL CYANIDEhttps://gsrs.ncats.nih.gov/ginas/app/beta/substances/7JP1R2F6C6
- Hazardous Substances Data Bank (HSDB)ALPHA-BROMOBENZYL CYANIDEhttps://pubchem.ncbi.nlm.nih.gov/source/hsdb/1982
- NJDOH RTK Hazardous Substance Listbromobenzyl cyanidehttp://nj.gov/health/eoh/rtkweb/documents/fs/0259.pdf
- Haz-Map, Information on Hazardous Chemicals and Occupational DiseasesLICENSECopyright (c) 2022 Haz-Map(R). All rights reserved. Unless otherwise indicated, all materials from Haz-Map are copyrighted by Haz-Map(R). No part of these materials, either text or image may be used for any purpose other than for personal use. Therefore, reproduction, modification, storage in a retrieval system or retransmission, in any form or by any means, electronic, mechanical or otherwise, for reasons other than personal use, is strictly prohibited without prior written permission.https://haz-map.com/AboutBromobenzyl cyanidehttps://haz-map.com/Agents/1456
- Toxin and Toxin Target Database (T3DB)LICENSET3DB is offered to the public as a freely available resource. Use and re-distribution of the data, in whole or in part, for commercial purposes requires explicit permission of the authors and explicit acknowledgment of the source material (T3DB) and the original publication.http://www.t3db.ca/downloadsBromobenzyl cyanidehttp://www.t3db.ca/toxins/T3D1693
- Emergency Response Guidebook (ERG)Bromobenzyl cyanideshttps://pubchem.ncbi.nlm.nih.gov/erg/
- ChEMBLLICENSEAccess to the web interface of ChEMBL is made under the EBI's Terms of Use (http://www.ebi.ac.uk/Information/termsofuse.html). The ChEMBL data is made available on a Creative Commons Attribution-Share Alike 3.0 Unported License (http://creativecommons.org/licenses/by-sa/3.0/).http://www.ebi.ac.uk/Information/termsofuse.htmlChEMBL Protein Target Treehttps://www.ebi.ac.uk/chembl/g/#browse/targets
- Japan Chemical Substance Dictionary (Nikkaji)
- PharosLICENSEData accessed from Pharos and TCRD is publicly available from the primary sources listed above. Please respect their individual licenses regarding proper use and redistribution.https://pharos.nih.gov/aboutbromobenzyl cyanidehttps://pharos.nih.gov/ligands/324F122CSCRP
- SpectraBase2-Bromanyl-2-phenyl-ethanenitrilehttps://spectrabase.com/spectrum/4bIQXf2cR6W2-Bromanyl-2-phenyl-ethanenitrilehttps://spectrabase.com/spectrum/4rBF3jNSZbw
- Springer Nature
- Thieme ChemistryLICENSEThe Thieme Chemistry contribution within PubChem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.https://creativecommons.org/licenses/by-nc-nd/4.0/
- Wikidatabromobenzyl cyanidehttps://www.wikidata.org/wiki/Q425589
- WikipediaBromobenzyl cyanidehttps://en.wikipedia.org/wiki/Bromobenzyl_cyanide
- PubChem
- GHS Classification (UNECE)GHS Classification Treehttp://www.unece.org/trans/danger/publi/ghs/ghs_welcome_e.html
- NORMAN Suspect List ExchangeLICENSEData: CC-BY 4.0; Code (hosted by ECI, LCSB): Artistic-2.0https://creativecommons.org/licenses/by/4.0/NORMAN Suspect List Exchange Classificationhttps://www.norman-network.com/nds/SLE/
- EPA Substance Registry ServicesEPA SRS List Classificationhttps://sor.epa.gov/sor_internet/registry/substreg/LandingPage.do
- MolGenieMolGenie Organic Chemistry Ontologyhttps://github.com/MolGenie/ontology/
- PATENTSCOPE (WIPO)SID 403449696https://pubchem.ncbi.nlm.nih.gov/substance/403449696
- NCBI