Dichlorotetrafluoroethane
- C2Cl2F4
- ClF2C-CClF2
- Dichlorotetrafluoroethane
- 1,2-Dichlorotetrafluoroethane
- 76-14-2
- Cryofluorane
- 1,2-Dichloro-1,1,2,2-tetrafluoroethane
- Create:2005-03-27
- Modify:2025-01-25
C2Cl2F4
ClF2C-CClF2
- 1,2-dichloro-1,1,2,2-tetrafluoroethane
- 1,2-dichlorotetrafluoroethane
- CFC 114
- CFC-114
- cryofluorane
- FLUOROCARBON 114
- Freon 114
- Frigiderm
- Dichlorotetrafluoroethane
- 1,2-Dichlorotetrafluoroethane
- 76-14-2
- Cryofluorane
- 1,2-Dichloro-1,1,2,2-tetrafluoroethane
- CFC-114
- Refrigerant 114
- Frigiderm
- FREON 114
- Halocarbon 114
- Propellant 114
- Fluorocarbon 114
- Fluorane 114
- Genetron 114
- Genetron 316
- Arcton 33
- Criofluorano
- Cryfluorane
- Cryofluorane [INN]
- Cryoflurane
- Arcton 114
- Frigen 114
- Ethane, 1,2-dichloro-1,1,2,2-tetrafluoro-
- Caswell No. 326A
- Ledon 114
- F 114 (halocarbon)
- R 114 (halocarbon)
- Ucon 114
- Cryofluoranum [INN-Latin]
- sym-Dichlorotetrafluoroethane
- tetrafluordichlorethan
- Criofluorano [INN-Spanish]
- Cryofluorane (INN)
- CCRIS 8973
- HSDB 146
- Chlorofluorocarbon 114
- CFC 114
- FKW 114
- Ethane, 1,2-dichlorotetrafluoro-
- UNII-6B5VVT93AR
- F 114
- EINECS 200-937-7
- FC 114
- Refrigerant R114
- Dichlorotetrafluoroethane [NF]
- NSC-760428
- BRN 1740333
- Isotron 114
- 1,1,2,2-Tetrafluoro-1,2-dichloroethane
- R 114
- CRYOFLUORANE [MI]
- s-Dichlorotetrafluoroethane
- 6B5VVT93AR
- (CF2Cl)2
- CRYOFLUORANE [MART.]
- Dichlorotetrafluoroethane (NF)
- DTXSID8026434
- P-114
- 4-01-00-00137 (Beilstein Handbook Reference)
- Dichloro-1,1,2,2-tetrafluoroethane
- DICHLOROTETRAFLUOROETHANE [II]
- 1,2-DICHLOROTETRAFLUORO-ETHANE
- NSC 760428
- TETRAFLUORDICHLORETHAN [WHO-DD]
- DICHLOROTETRAFLUOROETHANE [HSDB]
- DICHLOROTETRAFLUOROETHANE [VANDF]
- Cryofluoranum (INN-Latin)
- Criofluorano (INN-Spanish)
- CRYOFLUORANE (MART.)
- Cryofluoranum [Latin]
- Cryofluoranum
- DICHLOROTETRAFLUOROETHANE (II)
- UN1958
- EPA Pesticide Chemical Code 326200
- Cryofluoran
- FREON-114
- 1,2-Dichlorotetrafluoroethane Solution, 2000 microg/mL in Methanol
- Dwuchloroczterofluoroetan [Polish]
- Genetron114
- Fluorocarbon-114
- EINECS 215-300-9
- Caswell No 326A
- Freon114
- Halon242
- CClF2CClF2
- dichlortetrafluoroethane
- Dwuchloroczterofluoroetan
- Halon 242
- Flon-114
- 1,2-Dichloro-1,1,2,2-tetrafluoro-ethane
- SCHEMBL865
- symDichlorotetrafluoroethane
- 1,2dichlorotetrafluoroethane
- UNII-WG83EP1472
- Ethane, 1,2dichlorotetrafluoro
- CFC114
- CHEMBL325436
- DTXCID906434
- FRON 114
- REFRIGERANT GAS R-114
- DTXSID5041857
- HMS3264G16
- Pharmakon1600-01502370
- 1,2-DICHLOROPERFLUOROETHANE
- MFCD00000778
- NSC760428
- 1,1,2,2Tetrafluoro1,2dichloroethane
- 1,2Dichloro1,1,2,2tetrafluoroethane
- AKOS015915972
- CCG-213721
- Dichlorotetrafluoroethane (ACGIH:OSHA)
- Ethane, 1,2dichloro1,1,2,2tetrafluoro
- 1,2-Dichlorotetrafluoroethane, >=99.5%
- DB-056030
- 76-14-2; 1320-37-2(mixedisomers)
- D0417
- NS00041206
- D03790
- AB01563180_01
- Q420380
- SR-01000944235
- SR-01000944235-1
- 1,2-Dichlorotetrafluoroethane 100 microg/mL in Methanol
- 19F nuclear magnetic resonance spectrum
- Schoenflies notation
- Boiling point
- Chemical bond
- Chemical diffusion
- Chemical shift
- Density
- Diamagnetic susceptibility
- Dielectric constant
- Diffusion
- Diffusive flux
- Fusion temperature
- Heat of sublimation
- Internuclear distance
- Magnetic susceptibility
- Melting temperature
- Molecular structure
- Optical coefficient
- Phase diagram
- Phase equilibrium
- Phase transition
- Point group
- Refractive index
- Spin-spin coupling constant
- Surface tension
- Thermal expansion coefficient
- Transition enthalpy
- Vapor pressure
- Vapor-liquid equilibrium
- Virial coefficient
- Viscosity
2019: 1,000,000 lb - <20,000,000 lb
2018: 1,000,000 lb - <20,000,000 lb
2017: 1,000,000 lb - <20,000,000 lb
2016: 1,000,000 lb - <20,000,000 lb
- The numbers in the "ODP1" column are from the Montreal Protocol. Some numbers have been updated as per amendments to the protocol. The "ODP2" column numbers are from the stratospheric ozone protection regulations at 40 CFR Part 82, as required by Title VI of the Clean Air Act amendments. These numbers include the amendments of July 18, 2003 (68 FR 42892). Data in the "ODP3" column come from WMO's /World Meteorological Organization/ Scientific Assessment of Ozone Depletion: 2006. ODP values listed are semi-empirical and can be found in Table 8-1 of the document. All GWP values represent global warming potential over a 100-year time horizon. The numbers in the "GWP1" column are from Table 1-6 of The Scientific Assessment of Ozone Depletion, 2002, a report of the World Meteorological Association's Global Ozone Research and Monitoring Project. The GWPs in the "GWP1" column that were not provided Table 1-6 of the 2002 report have not been updated since 1998 and are from The Scientific Assessment of Ozone Depletion, 1998. "GWP2" column numbers are from the Intergovernmental Panel on Climate Change Third Assessment Report: Climate Change 2001, and "GWP3" column numbers are from 40 CFR Part 82, stratospheric ozone protection regulations required by Title VI of the Clean Air Act amendments. The data in the "GWP4" column come from the IPCC Special Report on Safeguarding the Ozone Layer and the Global Climate System: Issues related to Hydrofluorocarbons and Perfluorocarbons ("SROC"). The values listed are for direct radiative forcing and can be found in Table 2.7 in the document. The numbers in the "GWP5" column come from the WMO's Scientific Assessment of Ozone Depletion: 2006. The values listed are for direct radiative forcing and can be found in Table 8-2 of the document.
- Table: Class I Ozone-depleting Substances Chemical NameLifetime, in yearsODP3 (WMO 2006)ODP2 (40 CFR 82)ODP1 (Montreal Protocol)GWP5( WMO 2006)GWP4 (SROC)GWP3 (40 CFR)GWP2 (TAR)GWP1 (WMO 2002)Chemical NameCFC-114 DichlorotetrafluoroethaneLifetime, in years300ODP3 (WMO 2006)1ODP2 (40 CFR 82)1ODP1 (Montreal Protocol)1GWP5( WMO 2006)10040GWP4 (SROC)6030GWP3 (40 CFR)9300GWP2 (TAR)9800GWP1 (WMO 2002)9880
P410+P403, and P502
(The corresponding statement to each P-code can be found at the GHS Classification page.)
Aggregated GHS information provided per 119 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown.
Press. Gas (Liq.) (100%)
Ozone 1 (32.8%)
· Vapors may cause dizziness or asphyxiation without warning, especially when in closed or confined areas.
· Vapors from liquefied gas are initially heavier than air and spread along ground.
· Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite.
· Fire may produce irritating, corrosive and/or toxic gases.
Excerpt from ERG Guide 126 [Gases - Compressed or Liquefied (Including Refrigerant Gases)]:
Some may burn but none ignite readily. Containers may explode when heated. Ruptured cylinders may rocket. CAUTION: Aerosols (UN1950) may contain a flammable propellant. (ERG, 2024)
· Some may burn but none ignite readily.
· Containers may explode when heated.
· Ruptured cylinders may rocket.
CAUTION: Aerosols (UN1950) may contain a flammable propellant.
INHALATION: Remove to fresh air. If breathing has stopped, give artificial respiration. If breathing is difficult, give oxygen.
EYES: Flush with water for at least 15 minutes.
SKIN: Remove contaminated clothing and shoes. Wash affected areas with soap and water. (USCG, 1999)
General First Aid:
· Call 911 or emergency medical service.
· Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and avoid contamination.
· Move victim to fresh air if it can be done safely.
· Administer oxygen if breathing is difficult.
· If victim is not breathing:
-- DO NOT perform mouth-to-mouth resuscitation; the victim may have ingestedor inhaled the substance.
-- If equipped and pulse detected, wash face and mouth, then give artificial respiration using a proper respiratory medical device (bag-valve mask, pocket mask equipped with a one-way valve or other device).
-- If no pulse detected or no respiratory medical device available, provide continuouscompressions. Conduct a pulse check every two minutes or monitor for any signs of spontaneous respirations.
· Remove and isolate contaminated clothing and shoes.
· For minor skin contact, avoid spreading material on unaffected skin.
· In case of contact with substance, remove immediately by flushing skin or eyes with running water for at least 20 minutes.
· For severe burns, immediate medical attention is required.
· Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed.
· Keep victim calm and warm.
· Keep victim under observation.
· For further assistance, contact your local Poison Control Center.
· Note: Basic Life Support (BLS) and Advanced Life Support (ALS) should be done by trained professionals.
Specific First Aid:
· In case of contact with liquefied gas, only medical personnel should attempt thawing frosted parts.
(See general first aid procedures)
Eye: Frostbite - If eye tissue is frozen, seek medical attention immediately; if tissue is not frozen, immediately and thoroughly flush the eyes with large amounts of water for at least 15 minutes, occasionally lifting the lower and upper eyelids. If irritation, pain, swelling, lacrimation, or photophobia persist, get medical attention as soon as possible.
Skin: Frostbite - Compressed gases may create low temperatures when they expand rapidly. Leaks and uses that allow rapid expansion may cause a frostbite hazard. Wear appropriate personal protective clothing to prevent the skin from becoming frozen.
Breathing: Respiratory support
Excerpt from ERG Guide 126 [Gases - Compressed or Liquefied (Including Refrigerant Gases)]:
Use extinguishing agent suitable for type of surrounding fire.
SMALL FIRE: Dry chemical or CO2.
LARGE FIRE: Water spray, fog or regular foam. If it can be done safely, move undamaged containers away from the area around the fire. Damaged cylinders should be handled only by specialists.
FIRE INVOLVING TANKS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Do not direct water at source of leak or safety devices; icing may occur. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks in direct contact with flames. Some of these materials, if spilled, may evaporate leaving a flammable residue. (ERG, 2024)
· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
· Keep unauthorized personnel away.
· Stay upwind, uphill and/or upstream.
· Many gases are heavier than air and will spread along the ground and collect in low or confined areas (sewers, basements, tanks, etc.).
· Ventilate closed spaces before entering, but only if properly trained and equipped.
· Do not touch or walk through spilled material.
· Stop leak if you can do it without risk.
· Do not direct water at spill or source of leak.
· Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material.
· If possible, turn leaking containers so that gas escapes rather than liquid.
· Prevent entry into waterways, sewers, basements or confined areas.
· Allow substance to evaporate.
· Ventilate the area.
Excerpt from ERG Guide 126 [Gases - Compressed or Liquefied (Including Refrigerant Gases)]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 100 meters (330 feet) in all directions.
LARGE SPILL: Consider initial downwind evacuation for at least 500 meters (1/3 mile).
FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)
Immediate precautionary measure
· Isolate spill or leak area for at least 100 meters (330 feet) in all directions.
Large Spill
· Consider initial downwind evacuation for at least 500 meters (1/3 mile).
Fire
· If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.
Excerpt from ERG Guide 126 [Gases - Compressed or Liquefied (Including Refrigerant Gases)]:
Do not touch or walk through spilled material. Stop leak if you can do it without risk. Do not direct water at spill or source of leak. Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. If possible, turn leaking containers so that gas escapes rather than liquid. Prevent entry into waterways, sewers, basements or confined areas. Allow substance to evaporate. Ventilate the area. (ERG, 2024)
· Wear positive pressure self-contained breathing apparatus (SCBA).
· Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE.
· Structural firefighters' protective clothing provides thermal protection but only limited chemical protection.
15000.0 [ppm]
Excerpts from Documentation for IDLHs: Cardiac sensitization has been induced with endogenous epinephrine at 50,000 to 800,000 ppm [Mullin et al. 1972; Reinhardt et al. 1971].
15,000 ppm
See: 76142
· Use extinguishing agent suitable for type of surrounding fire.
Small Fire
· Dry chemical or CO2.
Large Fire
· Water spray, fog or regular foam.
· If it can be done safely, move undamaged containers away from the area around the fire.
· Damaged cylinders should be handled only by specialists.
Fire Involving Tanks
· Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles.
· Cool containers with flooding quantities of water until well after fire is out.
· Do not direct water at source of leak or safety devices; icing may occur.
· Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
· ALWAYS stay away from tanks in direct contact with flames.
· Some of these materials, if spilled, may evaporate leaving a flammable residue.
(See personal protection and sanitation codes)
Skin: Frostbite - Compressed gases may create low temperatures when they expand rapidly. Leaks and uses that allow rapid expansion may cause a frostbite hazard. Wear appropriate personal protective clothing to prevent the skin from becoming frozen.
Eyes: Frostbite - Wear appropriate eye protection to prevent eye contact with the liquid that could result in burns or tissue damage from frostbite.
Wash skin: No recommendation
Remove: No recommendation
Change: No recommendation
Provide: Frostbite wash - Quick drench facilities and/or eyewash fountains should be provided within the immediate work area for emergency use where there is any possibility of exposure to liquids that are extremely cold or rapidly evaporating.
NIOSH/OSHA
Up to 10000 ppm:
(APF = 10) Any supplied-air respirator
Up to 15000 ppm:
(APF = 25) Any supplied-air respirator operated in a continuous-flow mode
(APF = 50) Any self-contained breathing apparatus with a full facepiece
(APF = 50) Any supplied-air respirator with a full facepiece
Emergency or planned entry into unknown concentrations or IDLH conditions:
(APF = 10,000) Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode
(APF = 10,000) Any supplied-air respirator that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained positive-pressure breathing apparatus
Escape:
(APF = 50) Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted organic vapor canister
Any appropriate escape-type, self-contained breathing apparatus
Neurotoxin - Acute solvent syndrome
Occupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.
Other Poison - Simple Asphyxiant
ACGIH Carcinogen - Not Classifiable.
Solvents, acute toxic effect [Category: Acute Poisoning]
Asphyxiation, simple [Category: Acute Poisoning]
Patents are available for this chemical structure:
https://patentscope.wipo.int/search/en/result.jsf?inchikey=DDMOUSALMHHKOS-UHFFFAOYSA-N
- Australian Industrial Chemicals Introduction Scheme (AICIS)Ethane, 1,2-dichloro-1,1,2,2-tetrafluoro-https://services.industrialchemicals.gov.au/search-inventory/
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- ILO-WHO International Chemical Safety Cards (ICSCs)DICHLOROTETRAFLUOROETHANEhttps://www.ilo.org/dyn/icsc/showcard.display?p_version=2&p_card_id=0649
- CAS Common ChemistryLICENSEThe data from CAS Common Chemistry is provided under a CC-BY-NC 4.0 license, unless otherwise stated.https://creativecommons.org/licenses/by-nc/4.0/Dichlorotetrafluoroethanehttps://commonchemistry.cas.org/detail?cas_rn=1320-37-2
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- EPA Chemicals under the TSCAEthane, 1,2-dichloro-1,1,2,2-tetrafluoro-https://www.epa.gov/chemicals-under-tscaEPA TSCA Classificationhttps://www.epa.gov/tsca-inventory
- EPA DSSTox1,2-Dichloro-1,1,2,2-tetrafluoroethanehttps://comptox.epa.gov/dashboard/DTXSID8026434CompTox Chemicals Dashboard Chemical Listshttps://comptox.epa.gov/dashboard/chemical-lists/
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- Hazardous Substances Data Bank (HSDB)1,2-DICHLORO-1,1,2,2-TETRAFLUOROETHANEhttps://pubchem.ncbi.nlm.nih.gov/source/hsdb/146
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- NJDOH RTK Hazardous Substance Listdichlorotetrafluoroethanehttp://nj.gov/health/eoh/rtkweb/documents/fs/0671.pdf
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- Emergency Response Guidebook (ERG)1,2-Dichloro-1,1,2,2-tetrafluoroethanehttps://pubchem.ncbi.nlm.nih.gov/erg/
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- NITE-CMCDichlorotetrafluoroethane - FY2006 (New/original classication)https://www.chem-info.nite.go.jp/chem/english/ghs/06-imcg-0392e.htmlEthane, 1,2-dichlorotetrafluoro- - FY2006 (New/original classication)https://www.chem-info.nite.go.jp/chem/english/ghs/06-imcg-0767e.htmlDichlorotetrafluoroethane (isomer mixture) - FY2019 (Revised classification)https://www.chem-info.nite.go.jp/chem/english/ghs/19-mhlw-2112e.html
- Japan Chemical Substance Dictionary (Nikkaji)
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- SpectraBaseETHANE, 1,2-DICHLORO-1,1,2,2-TETRAFLUORO-https://spectrabase.com/spectrum/KnUTWq8lv5sEthane, 1,2-dichloro-1,1,2,2-tetrafluoro-https://spectrabase.com/spectrum/ElNIEv9xsNE1,1,2,2-TETRAFLUORO-1,2-DICHLOROETHANEhttps://spectrabase.com/spectrum/6TCqGdkdeTG1,2-DICHLOROTETRAFLUOROETHANE (F114)https://spectrabase.com/spectrum/5nptSoMj0vI1,2-DICHLOROTETRAFLUOROETHANEhttps://spectrabase.com/spectrum/2fx2bA5iw0I1,2-DICHLORO-1,1,2,2-TETRAFLUOROETHANEhttps://spectrabase.com/spectrum/J1gvwCun0Wy
- NMRShiftDB
- Springer Nature
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- Medical Subject Headings (MeSH)LICENSEWorks produced by the U.S. government are not subject to copyright protection in the United States. Any such works found on National Library of Medicine (NLM) Web sites may be freely used or reproduced without permission in the U.S.https://www.nlm.nih.gov/copyright.html
- GHS Classification (UNECE)GHS Classification Treehttp://www.unece.org/trans/danger/publi/ghs/ghs_welcome_e.html
- NORMAN Suspect List ExchangeLICENSEData: CC-BY 4.0; Code (hosted by ECI, LCSB): Artistic-2.0https://creativecommons.org/licenses/by/4.0/NORMAN Suspect List Exchange Classificationhttps://www.norman-network.com/nds/SLE/
- EPA Substance Registry ServicesEPA SRS List Classificationhttps://sor.epa.gov/sor_internet/registry/substreg/LandingPage.do
- MolGenieMolGenie Organic Chemistry Ontologyhttps://github.com/MolGenie/ontology/
- PATENTSCOPE (WIPO)SID 403382532https://pubchem.ncbi.nlm.nih.gov/substance/403382532
- NCBI