Phosmet
- Phosmet
- Fosmet
- 732-11-6
- Decemthion
- Phthalophos
- Create:2005-03-27
- Modify:2025-01-11
- Imidan
- N-(Mercaptomethyl)phthalimide S-(O,O-dimethyl phosphorothionate)
- Phosmet
- Phthalophos
- Prolate
- Phosmet
- Fosmet
- 732-11-6
- Decemthion
- Phthalophos
- Imidathion
- Percolate
- Prolate
- IMIDAN
- Ftalophos
- Kemolate
- Safidon
- Simidan
- Smidan
- Decemthion P-6
- PMP (Pesticide)
- Phtalofos
- Prolate E
- Stauffer R 1504
- Imidan WP
- Prolate 5 Dust
- Decemtion P-6
- Imidan 5 Dust
- O,O-Dimethyl S-phthalimidomethyl phosphorodithioate
- Prolate 8-OS
- O,O-Dimethyl phthalimidomethyl phosphorodithioate
- Caswell No. 543
- O,O-Dimethyl S-(phthalimidomethyl) dithiophosphate
- Phosmet [BAN]
- phthalimidomethyl-o,o-dimethyl phosphorodithioate
- CCRIS 5295
- ENT 25,705
- HSDB 1734
- Phthalimido O,O-dimethyl phosphorodithioate
- EINECS 211-987-4
- UNII-VN04LI540Y
- R 1504
- EPA Pesticide Chemical Code 059201
- Phthalimidomethyl O,O-dimethyl phosphorodithioate
- (O,O-Dimethyl-phthalimidiomethyl-dithiophosphate)
- 2-(dimethoxyphosphinothioylsulfanylmethyl)isoindole-1,3-dione
- BRN 0264869
- VN04LI540Y
- DTXSID5024261
- CHEBI:38786
- O,O-Dimethyl S-(N-phthalimidomethyl)dithiophosphate
- O,O-Dimethyl S-(phthalimidomethyl)phosphorodithioate
- AI3-25705
- R-1504
- N-(Dimethoxyphosphinothioylthiomethyl)phthalimide
- O,O-Dimethyl S-phthalimidomethyl phosphorothionate
- SMR000054364
- O,O-Dimethyl S-(phthalimididomethyl)phosphorodithioate
- Phthalimide, N-(mercaptomethyl)-, S-ester with O,O-dimethyl phosphorodithioate
- MLS000104429
- MLS001074294
- Phosphorodithioic acid, O,O-dimethyl ester, S-ester with N-(mercaptomethyl)phthalimide
- Phosphorodithioic acid, S-((1,3-dihydro-1,3-dioxo-isoindol-2-yl)methyl) O,O-dimethyl ester
- S-((1,3-Dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl) O,O-dimethyl phosphorodithioate
- DTXCID004261
- N-(Mercaptomethyl)phthalimide S-(O,O-dimethyl phosphorodithioate)
- O,O-Dimethyl phosphorodithioate S-ester with N-(mercaptomethyl)phthalimide
- S-((1,3-Dioxo-2H-isoindol-2-yl)methyl) O,O-dimethyl phosphorodithioate
- Phosmet (BAN)
- S-[(1,3-Dioxo-1,3-dihydro-2H-isoindol-2-yl)methyl] o,o-dimethyl dithiophosphate
- Phosphorodithioic acid O,O-dimethyl ester S-ester with N-(mercaptomethyl) phthalimide
- Phosphorodithioic acid, S-((1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl) O,O-dimethyl ester
- S-((1,3-Dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl) O,O-dimethy phosphorodithioate
- S-((1,3-Dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl)phosphorodithioic acid O,O-dimethyl ester
- S-[(1,3-dioxo-1,3-dihydro-2H-isoindol-2-yl)methyl] O,O-dimethyl phosphorodithioate
- NCGC00080392-01
- PHOSMET (MART.)
- PHOSMET [MART.]
- Phosphorodithioic acid, S-[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl] O,O-dimethyl ester
- N-(Mercaptomethyl)phthalimide S-(O,O-dimethyl) phosphorodithioate
- N-(MERCAPTOMETHYL) PHTHALIMIDE S-(O,O-DIMETHYL PHOSPHORODITHIOATE)
- 5104-30-3
- CAS-732-11-6
- Phosmet-d6 100 Amicrog/mL in Acetone
- Phosmet [BSI:ISO]
- SR-01000195222
- Phosmet [BAN:BSI:ISO]
- Del-Phos
- S-((1,3-dioxo-1,3-dihydro-2H-isoindol-2-yl)methyl) O,O-dimethyl dithiophosphate
- S-((1,3-dioxo-1,3-dihydro-2H-isoindol-2-yl)methyl) O,O-dimethyl phosphorodithioate
- Prolate I-E
- DECEMTHIO
- DECEMTION
- ORBISECT
- ORDATOX
- PORECT
- Poron (TN)
- Del-Phos (TN)
- PHOSMET [HSDB]
- PHOSMET [ISO]
- PHOSMET [MI]
- Opera_ID_1806
- CBMicro_004801
- DECEMTHION EK 20
- STARBAR GX 118
- SCHEMBL3620
- Oprea1_616683
- PHOSMET [GREEN BOOK]
- cid_12901
- CHEMBL1481873
- BDBM79427
- LMNZTLDVJIUSHT-UHFFFAOYSA-
- HMS2230D06
- HMS3370L13
- N-(Mercaptomethyl)phthalimide S-(O,O-dimethyl phosphorothionate)
- SMSF0003235
- Tox21_110993
- Tox21_202316
- Tox21_300093
- ENT 25705
- Phosmet 10 microg/mL in Cyclohexane
- Phosmet 1000 microg/mL in Acetone
- STK097158
- AKOS001603761
- Phosmet 100 microg/mL in Cyclohexane
- Tox21_110993_1
- USEPA/OPP Pesticide Code: 59201
- CB06771
- DB11448
- Phosmet 100 microg/mL in Acetonitrile
- NCGC00080392-02
- NCGC00080392-03
- NCGC00080392-04
- NCGC00080392-05
- NCGC00254165-01
- NCGC00259865-01
- BIM-0004802.P001
- DB-055733
- Phosmet, PESTANAL(R), analytical standard
- NS00000517
- C18756
- D08372
- O,O-Dimethyl 5-(phthalimidomethyl)dithiophosphate
- O,O-Dimethyl S-(phthalimidomethyl)dithiophosphate
- Q421379
- o,o-dimethyl s-(n-phthalimidomethyl) dithiophosphate
- O,O-dimethyl S-phthalimido methyl phosphorodithioate
- SR-01000195222-1
- SR-01000195222-4
- W-104463
- (O,O-DIMETHYL-PHTHALIMIDIOMETHYLDITHIOPHOSPHATE)
- 2-[(dimethoxyphosphinothioylthio)methyl]isoindole-1,3-dione
- S-PHTHALIMIDOMETHYL O,O-DIMETHYL PHOSPHORODITHIOATE
- 2-[(dimethoxythiophosphorylthio)methyl]isoindoline-1,3-quinone
- N-(mercaptomethyl)phthalamide S-(O,O-dimethyl phosphorodithioate)
- S-(1,3-dioxoisoindolin-2-yl)methyl O,O-dimethyl phosphorodithioate
- O,O-Dimethyl phosphorodithioate S-ester with N-(mercaptomethyl) phthalimide
- PHOSPHORODITHIOIC ACID, O,O-DIMETHYL S-PHTHALIMIDOMETHYL ESTER
- S-[(1,3-Dioxo-1,3-dihydro-2H-isoindol-2-yl)methyl] O,O-dimethyl dithiophosphate #
- InChI=1/C11H12NO4PS2/c1-15-17(18,16-2)19-7-12-10(13)8-5-3-4-6-9(8)11(12)14/h3-6H,7H2,1-2H3
159.32 Ų [M+H]+
167.89 Ų [M+Na]+
133.0284 100
95.0492 89.11
105.0336 68.38
160.0393 67.25
105.0447 17.56
160.0393 100
133.0285 6.51
105.0336 1.03
160.0393 999
178.05 5
113.0596 1
160.0393 999
133.0283 5
178.05 5
142.9931 1
105.0335 1
H301 (32.6%): Toxic if swallowed [Danger Acute toxicity, oral]
H302+H312 (42.7%): Harmful if swallowed or in contact with skin [Warning Acute toxicity, oral; acute toxicity, dermal]
H302 (67.4%): Harmful if swallowed [Warning Acute toxicity, oral]
H312 (68.5%): Harmful in contact with skin [Warning Acute toxicity, dermal]
H330 (43.8%): Fatal if inhaled [Danger Acute toxicity, inhalation]
H332 (31.5%): Harmful if inhaled [Warning Acute toxicity, inhalation]
H361f (32.6%): Suspected of damaging fertility [Warning Reproductive toxicity]
H370 (32.6%): Causes damage to organs [Danger Specific target organ toxicity, single exposure]
H400 (100%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]
H410 (100%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]
P203, P260, P261, P264, P270, P271, P273, P280, P284, P301+P316, P301+P317, P302+P352, P304+P340, P308+P316, P316, P317, P318, P320, P321, P330, P362+P364, P391, P403+P233, P405, and P501
(The corresponding statement to each P-code can be found at the GHS Classification page.)
Aggregated GHS information provided per 89 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown.
Acute Tox. 3 (32.6%)
Acute Tox. 4 (67.4%)
Acute Tox. 4 (68.5%)
Acute Tox. 2 (43.8%)
Acute Tox. 4 (31.5%)
Repr. 2 (32.6%)
STOT SE 1 (32.6%)
Aquatic Acute 1 (100%)
Aquatic Chronic 1 (100%)
Reproductive toxicity - category 2
Acute toxicity (inhalation) - category 4
Acute toxicity (ingestion) - category 3
Specific target organ toxicity (single exposure) - category 1
Hazardous to the aquatic environment (acute) - category 1
Hazardous to the aquatic environment (chronic) - category 1
Note: Phosmet is a cholinesterase inhibitor.
Signs and Symptoms of Acute Phosmet Exposure: Acute exposure to phosmet may produce the following signs and symptoms: pinpoint pupils, blurred vision, headache, dizziness, muscle spasms, and profound weakness. Vomiting, diarrhea, abdominal pain, seizures, and coma may also occur. The heart rate may decrease following oral exposure or increase following dermal exposure. Chest pain may be noted. Hypotension (low blood pressure) may occur, although hypertension (high blood pressure) is not uncommon. Dyspnea (shortness of breath) may be followed by respiratory collapse. Giddiness is common.
Emergency Life-Support Procedures: Acute exposure to phosmet may require decontamination and life support for the victims. Emergency personnel should wear protective clothing appropriate to the type and degree of contamination. Air-purifying or supplied-air respiratory equipment should also be worn, as necessary. Rescue vehicles should carry supplies such as plastic sheeting and disposable plastic bags to assist in preventing spread of contamination.
Inhalation Exposure:
1. Move victims to fresh air. Emergency personnel should avoid self-exposure to phosmet.
2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer oxygen or other respiratory support.
3. Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures.
4. Transport to a health care facility.
Dermal/Eye Exposure:
1. Remove victims from exposure. Emergency personnel should avoid self- exposure to phosmet.
2. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer oxygen or other respiratory support.
3. Remove contaminated clothing as soon as possible.
4. If eye exposure has occurred, eyes must be flushed with lukewarm water for at least 15 minutes.
5. Wash exposed skin areas three times with soap and water.
6. Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures.
7. Transport to a health care facility.
Ingestion Exposure:
1. Evaluate vital signs including pulse and respiratory rate, and note any trauma. If no pulse is detected, provide CPR. If not breathing, provide artificial respiration. If breathing is labored, administer oxygen or other respiratory support.
2. Obtain authorization and/or further instructions from the local hospital for administration of an antidote or performance of other invasive procedures.
3. Vomiting may be induced with syrup of Ipecac. If elapsed time since ingestion of phosmet is unknown or suspected to be greater than 30 minutes, do not induce vomiting and proceed to Step
4. Ipecac should not be administered to children under 6 months of age.Warning: Ingestion of phosmet may result in sudden onset of seizures or loss of consciousness. Syrup of Ipecac should be administered only if victims are alert, have an active gag-reflex, and show no signs of impending seizure or coma. If ANY uncertainty exists, proceed to Step
4.The following dosages of Ipecac are recommended: children up to 1 year old, 10 mL (1/3 oz); children 1 to 12 years old, 15 mL (1/2 oz); adults, 30 mL (1 oz). Ambulate (walk) the victims and give large quantities of water. If vomiting has not occurred after 15 minutes, Ipecac may be readministered. Continue to ambulate and give water to the victims. If vomiting has not occurred within 15 minutes after second administration of Ipecac, administer activated charcoal.
4. Activated charcoal may be administered if victims are conscious and alert. Use 15 to 30 g (1/2 to 1 oz) for children, 50 to 100 g (1-3/4 to 3-1/2 oz) for adults, with 125 to 250 mL (1/2 to 1 cup) of water.
5. Promote excretion by administering a saline cathartic or sorbitol to conscious and alert victims. Children require 15 to 30 g (1/2 to 1 oz) of cathartic; 50 to 100 g (1-3/4 to 3-1/2 oz) is recommended for adults.
6. Transport to a health care facility. (EPA, 1998)
(Non-Specific -- Organophosphorus Pesticide, n.o.s.). Stay upwind; keep out of low areas. Move container from fire area if you can do it without risk. Fight fire from maximum distance. Dike fire control water for later disposal; do not scatter material. Wear positive pressure breathing apparatus and special protective clothing.
(Non-Specific -- Organophosphorus Pesticide, n.o.s.) This material may burn but does not ignite readily. For small fires, use dry chemical, carbon dioxide, water spray, or foam. For large fires, use water spray, fog, or foam. (EPA, 1998)
Excerpt from ERG Guide 171 [Substances (Low to Moderate Hazard)]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.
SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.
FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)
Caution : Phosmet may produce toxic gases when heated; containers may explode in the heat of fire. Avoid sources of extreme heat.
This is an organophosphorus pesticide. As for other organophosphorus pesticides stay upwind; keep out of low areas. Ventilate closed spaces before entering them. Remove and isolate contaminated clothing at the site. Do not touch spilled material. Use water spray to reduce vapors. Take up small spills with sand or other noncombustible absorbent material and place in containers for later disposal. Take up small, dry spills with clean shovel and place in clean, dry container. Dike far ahead of large spills for later disposal. (EPA, 1998)
Amides and Imides
Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters
Hazard Traits - Developmental Toxicity; Neurotoxicity
Authoritative List - CECBP - Priority Chemicals
Report - if used as a fragrance or flavor ingredient
IMAP assessments - Phosphorodithioic acid, S-[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl] O,O-dimethyl ester: Environment tier I assessment
IMAP assessments - Phosphorodithioic acid, S-[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl] O,O-dimethyl ester: Human health tier I assessment
Hepatic
Nervous
Hepatic
Nervous
Occupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.
Other Poison - Organophosphate
Patents are available for this chemical structure:
https://patentscope.wipo.int/search/en/result.jsf?inchikey=LMNZTLDVJIUSHT-UHFFFAOYSA-N
- Australian Industrial Chemicals Introduction Scheme (AICIS)Phosphorodithioic acid, S-[(1,3-dihydro-1,3-dioxo-2H-isoindol-2-yl)methyl] O,O-dimethyl esterhttps://services.industrialchemicals.gov.au/search-assessments/
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- NITE-CMCO,O-dimethyl phthalimidomethyl S-phosphorodithioate - FY2006 (New/original classication)https://www.chem-info.nite.go.jp/chem/english/ghs/06-imcg-1239e.htmlO,O-dimethyl phthalimidomethyl S-phosphorodithioate; Phosmet - FY2020 (Revised classification)https://www.chem-info.nite.go.jp/chem/english/ghs/20-mhlw-2071e.html
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