Chlorotrifluoromethane
- CHLOROTRIFLUOROMETHANE
- Trifluoromethyl chloride
- 75-72-9
- Trifluorochloromethane
- Monochlorotrifluoromethane
- Create:2005-03-27
- Modify:2025-01-25
- CHLOROTRIFLUOROMETHANE
- Trifluoromethyl chloride
- 75-72-9
- Trifluorochloromethane
- Monochlorotrifluoromethane
- Methane, chlorotrifluoro-
- chloro(trifluoro)methane
- Genetron 13
- Arcton 3
- CFC-13
- Frigen 13
- Freon 13
- Trifluoromonochlorocarbon
- Halocarbon 13/ucon 13
- Methane, monochlorotrifluoro-
- CF3Cl
- FC 13
- Khladon 13
- F 13
- R 13
- 7C6U91JNED
- Fluorocarbon 13
- HSDB 140
- CClF3
- EINECS 200-894-4
- UN1022
- UNII-7C6U91JNED
- BRN 1732392
- Refrigerant 13
- Halocarbon 13
- Chlorotrifluromethane
- MFCD00000773
- Trifluoro-chloro-methane
- REFRIGERANT-13
- FREON-13
- SCHEMBL27896
- 4-01-00-00034 (Beilstein Handbook Reference)
- Chlorotrifluoromethane, >=99%
- SCHEMBL3495970
- DTXSID4052500
- AFYPFACVUDMOHA-UHFFFAOYSA-
- AKOS015853107
- InChI=1/CClF3/c2-1(3,4)5
- TRIFLUOROMONOCHLOROCARBON [HSDB]
- UN 1022
- R-13
- NS00041084
- Chlorotrifluoromethane or Refrigerant gas R 13
- Q423046
- Chlorotrifluoromethane or Refrigerant gas R 13 [UN1022] [Nonflammable gas]
- 19F nuclear magnetic resonance spectrum
- Dunham energy parameter
- Schoenflies notation
- Absorbance
- Boiling point
- Centrifugal distortion
- Chemical bond
- Chemical diffusion
- Chemical shift
- Composition
- Density
- Diamagnetic susceptibility
- Dielectric constant
- Diffusion
- Diffusive flux
- Dispersion
- Electric dipole moment
- Excess enthalpy
- Heat of solution
- Heat of sublimation
- Internuclear distance
- Magnetic susceptibility
- Mixing enthalpy
- Molecular dipole moment
- Molecular structure
- Nuclear quadrupole coupling
- Nuclear quadrupole moment
- Nuclear quadrupole resonance spectroscopy
- Optical coefficient
- Phase diagram
- Phase equilibrium
- Phase transition
- Point group
- Potential energy
- Quadrupole coupling
- Refractive index
- Rotation-vibration spectrum
- Rotational excitation cross section
- Self-diffusion
- Sound absorption
- Sound propagation
- Sound velocity
- Spin-spin coupling constant
- Surface tension
- Thermal expansion coefficient
- Vapor pressure
- Vapor-liquid equilibrium
- Vibrational mode frequency
- Virial coefficient
- Viscosity
P410+P403, and P502
(The corresponding statement to each P-code can be found at the GHS Classification page.)
Aggregated GHS information provided per 112 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown.
Press. Gas (Liq.) (100%)
Ozone 1 (33.9%)
· Vapors may cause dizziness or asphyxiation without warning, especially when in closed or confined areas.
· Vapors from liquefied gas are initially heavier than air and spread along ground.
· Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite.
· Fire may produce irritating, corrosive and/or toxic gases.
· Some may burn but none ignite readily.
· Containers may explode when heated.
· Ruptured cylinders may rocket.
CAUTION: Aerosols (UN1950) may contain a flammable propellant.
INHALATION: Remove to fresh air. If breathing has stopped, give artificial respiration. If breathing is difficult, give oxygen.
SKIN: Wash affected areas with warm water. DO NOT USE HOT WATER. (USCG, 1999)
General First Aid:
· Call 911 or emergency medical service.
· Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and avoid contamination.
· Move victim to fresh air if it can be done safely.
· Administer oxygen if breathing is difficult.
· If victim is not breathing:
-- DO NOT perform mouth-to-mouth resuscitation; the victim may have ingestedor inhaled the substance.
-- If equipped and pulse detected, wash face and mouth, then give artificial respiration using a proper respiratory medical device (bag-valve mask, pocket mask equipped with a one-way valve or other device).
-- If no pulse detected or no respiratory medical device available, provide continuouscompressions. Conduct a pulse check every two minutes or monitor for any signs of spontaneous respirations.
· Remove and isolate contaminated clothing and shoes.
· For minor skin contact, avoid spreading material on unaffected skin.
· In case of contact with substance, remove immediately by flushing skin or eyes with running water for at least 20 minutes.
· For severe burns, immediate medical attention is required.
· Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed.
· Keep victim calm and warm.
· Keep victim under observation.
· For further assistance, contact your local Poison Control Center.
· Note: Basic Life Support (BLS) and Advanced Life Support (ALS) should be done by trained professionals.
Specific First Aid:
· In case of contact with liquefied gas, only medical personnel should attempt thawing frosted parts.
Excerpt from ERG Guide 126 [Gases - Compressed or Liquefied (Including Refrigerant Gases)]:
Use extinguishing agent suitable for type of surrounding fire.
SMALL FIRE: Dry chemical or CO2.
LARGE FIRE: Water spray, fog or regular foam. If it can be done safely, move undamaged containers away from the area around the fire. Damaged cylinders should be handled only by specialists.
FIRE INVOLVING TANKS: Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles. Cool containers with flooding quantities of water until well after fire is out. Do not direct water at source of leak or safety devices; icing may occur. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks in direct contact with flames. Some of these materials, if spilled, may evaporate leaving a flammable residue. (ERG, 2024)
· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
· Keep unauthorized personnel away.
· Stay upwind, uphill and/or upstream.
· Many gases are heavier than air and will spread along the ground and collect in low or confined areas (sewers, basements, tanks, etc.).
· Ventilate closed spaces before entering, but only if properly trained and equipped.
· Do not touch or walk through spilled material.
· Stop leak if you can do it without risk.
· Do not direct water at spill or source of leak.
· Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material.
· If possible, turn leaking containers so that gas escapes rather than liquid.
· Prevent entry into waterways, sewers, basements or confined areas.
· Allow substance to evaporate.
· Ventilate the area.
Excerpt from ERG Guide 126 [Gases - Compressed or Liquefied (Including Refrigerant Gases)]:
IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area for at least 100 meters (330 feet) in all directions.
LARGE SPILL: Consider initial downwind evacuation for at least 500 meters (1/3 mile).
FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024)
Immediate precautionary measure
· Isolate spill or leak area for at least 100 meters (330 feet) in all directions.
Large Spill
· Consider initial downwind evacuation for at least 500 meters (1/3 mile).
Fire
· If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions.
Excerpt from ERG Guide 126 [Gases - Compressed or Liquefied (Including Refrigerant Gases)]:
Do not touch or walk through spilled material. Stop leak if you can do it without risk. Do not direct water at spill or source of leak. Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. If possible, turn leaking containers so that gas escapes rather than liquid. Prevent entry into waterways, sewers, basements or confined areas. Allow substance to evaporate. Ventilate the area. (ERG, 2024)
· Wear positive pressure self-contained breathing apparatus (SCBA).
· Wear chemical protective clothing that is specifically recommended by the manufacturer when there is NO RISK OF FIRE.
· Structural firefighters' protective clothing provides thermal protection but only limited chemical protection.
· Use extinguishing agent suitable for type of surrounding fire.
Small Fire
· Dry chemical or CO2.
Large Fire
· Water spray, fog or regular foam.
· If it can be done safely, move undamaged containers away from the area around the fire.
· Damaged cylinders should be handled only by specialists.
Fire Involving Tanks
· Fight fire from maximum distance or use unmanned master stream devices or monitor nozzles.
· Cool containers with flooding quantities of water until well after fire is out.
· Do not direct water at source of leak or safety devices; icing may occur.
· Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank.
· ALWAYS stay away from tanks in direct contact with flames.
· Some of these materials, if spilled, may evaporate leaving a flammable residue.
Neurotoxin - Acute solvent syndrome
Other Poison - Simple Asphyxiant
Asphyxiation, simple [Category: Acute Poisoning]
Solvents, acute toxic effect [Category: Acute Poisoning]
Patents are available for this chemical structure:
https://patentscope.wipo.int/search/en/result.jsf?inchikey=AFYPFACVUDMOHA-UHFFFAOYSA-N
- Australian Industrial Chemicals Introduction Scheme (AICIS)Methane, chlorotrifluoro-https://services.industrialchemicals.gov.au/search-inventory/
- CAMEO ChemicalsLICENSECAMEO Chemicals and all other CAMEO products are available at no charge to those organizations and individuals (recipients) responsible for the safe handling of chemicals. However, some of the chemical data itself is subject to the copyright restrictions of the companies or organizations that provided the data.https://cameochemicals.noaa.gov/help/reference/terms_and_conditions.htm?d_f=falseCHLOROTRIFLUOROMETHANEhttps://cameochemicals.noaa.gov/chemical/2934CAMEO Chemical Reactivity Classificationhttps://cameochemicals.noaa.gov/browse/react
- ILO-WHO International Chemical Safety Cards (ICSCs)CHLOROTRIFLUOROMETHANEhttps://www.ilo.org/dyn/icsc/showcard.display?p_version=2&p_card_id=0420
- CAS Common ChemistryLICENSEThe data from CAS Common Chemistry is provided under a CC-BY-NC 4.0 license, unless otherwise stated.https://creativecommons.org/licenses/by-nc/4.0/Chlorotrifluoromethanehttps://commonchemistry.cas.org/detail?cas_rn=75-72-9
- ChemIDplusChlorotrifluoromethanehttps://pubchem.ncbi.nlm.nih.gov/substance/?source=chemidplus&sourceid=0000075729ChemIDplus Chemical Information Classificationhttps://pubchem.ncbi.nlm.nih.gov/source/ChemIDplus
- EPA Chemicals under the TSCAMethane, chlorotrifluoro-https://www.epa.gov/chemicals-under-tscaEPA TSCA Classificationhttps://www.epa.gov/tsca-inventory
- EPA DSSToxChlorotrifluoromethanehttps://comptox.epa.gov/dashboard/DTXSID4052500CompTox Chemicals Dashboard Chemical Listshttps://comptox.epa.gov/dashboard/chemical-lists/
- European Chemicals Agency (ECHA)LICENSEUse of the information, documents and data from the ECHA website is subject to the terms and conditions of this Legal Notice, and subject to other binding limitations provided for under applicable law, the information, documents and data made available on the ECHA website may be reproduced, distributed and/or used, totally or in part, for non-commercial purposes provided that ECHA is acknowledged as the source: "Source: European Chemicals Agency, http://echa.europa.eu/". Such acknowledgement must be included in each copy of the material. ECHA permits and encourages organisations and individuals to create links to the ECHA website under the following cumulative conditions: Links can only be made to webpages that provide a link to the Legal Notice page.https://echa.europa.eu/web/guest/legal-noticeChlorotrifluoromethanehttps://echa.europa.eu/substance-information/-/substanceinfo/100.000.814Chlorotrifluoromethane (EC: 200-894-4)https://echa.europa.eu/information-on-chemicals/cl-inventory-database/-/discli/details/92876
- FDA Global Substance Registration System (GSRS)LICENSEUnless otherwise noted, the contents of the FDA website (www.fda.gov), both text and graphics, are not copyrighted. They are in the public domain and may be republished, reprinted and otherwise used freely by anyone without the need to obtain permission from FDA. Credit to the U.S. Food and Drug Administration as the source is appreciated but not required.https://www.fda.gov/about-fda/about-website/website-policies#linkingCHLOROTRIFLUOROMETHANEhttps://gsrs.ncats.nih.gov/ginas/app/beta/substances/7C6U91JNED
- Hazardous Substances Data Bank (HSDB)CHLOROTRIFLUOROMETHANEhttps://pubchem.ncbi.nlm.nih.gov/source/hsdb/140
- New Zealand Environmental Protection Authority (EPA)LICENSEThis work is licensed under the Creative Commons Attribution-ShareAlike 4.0 International licence.https://www.epa.govt.nz/about-this-site/general-copyright-statement/
- NJDOH RTK Hazardous Substance Listchlorotrifluoromethanehttp://nj.gov/health/eoh/rtkweb/documents/fs/0425.pdf
- Emergency Response Guidebook (ERG)Chlorotrifluoromethanehttps://pubchem.ncbi.nlm.nih.gov/erg/
- Haz-Map, Information on Hazardous Chemicals and Occupational DiseasesLICENSECopyright (c) 2022 Haz-Map(R). All rights reserved. Unless otherwise indicated, all materials from Haz-Map are copyrighted by Haz-Map(R). No part of these materials, either text or image may be used for any purpose other than for personal use. Therefore, reproduction, modification, storage in a retrieval system or retransmission, in any form or by any means, electronic, mechanical or otherwise, for reasons other than personal use, is strictly prohibited without prior written permission.https://haz-map.com/AboutChlorotrifluoromethanehttps://haz-map.com/Agents/1551
- NITE-CMCChlorotrifluoromethane; CFC-13 - FY2006 (New/original classication)https://www.chem-info.nite.go.jp/chem/english/ghs/06-imcg-0378e.html
- Japan Chemical Substance Dictionary (Nikkaji)
- NIST Mass Spectrometry Data CenterLICENSEData covered by the Standard Reference Data Act of 1968 as amended.https://www.nist.gov/srd/public-lawChlorotrifluoromethanehttp://www.nist.gov/srd/nist1a.cfm
- SpectraBaseMethane, chlorotrifluoro-https://spectrabase.com/spectrum/EjJ2qwskQOxMethane, chlorotrifluoro-https://spectrabase.com/spectrum/6xOK1o8ESLvCHLORO-TRIFLUOROMETHANEhttps://spectrabase.com/spectrum/J1XOnnF2Si0CHLOROTRIFLUOROMETHANEhttps://spectrabase.com/spectrum/9F3Emok8uFsChlorotrifluoromethanehttps://spectrabase.com/spectrum/JMk4dXBqRtP
- NMRShiftDB
- Springer Nature
- SpringerMaterialsTrifluoro-chloro-methanehttps://materials.springer.com/substanceprofile/docs/smsid_kanwcringmzmuwli
- Thieme ChemistryLICENSEThe Thieme Chemistry contribution within PubChem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.https://creativecommons.org/licenses/by-nc-nd/4.0/
- Wikidatachlorotrifluoromethanehttps://www.wikidata.org/wiki/Q423046
- Wikipediachlorotrifluoromethanehttps://en.wikipedia.org/wiki/Chlorotrifluoromethane
- PubChemPFAS and Fluorinated Compounds in PubChemhttps://gitlab.com/uniluxembourg/lcsb/eci/pubchem-docs/-/raw/main/pfas-tree/PFAS_Tree.pdf?inline=false
- GHS Classification (UNECE)GHS Classification Treehttp://www.unece.org/trans/danger/publi/ghs/ghs_welcome_e.html
- NORMAN Suspect List ExchangeLICENSEData: CC-BY 4.0; Code (hosted by ECI, LCSB): Artistic-2.0https://creativecommons.org/licenses/by/4.0/NORMAN Suspect List Exchange Classificationhttps://www.norman-network.com/nds/SLE/
- EPA Substance Registry ServicesEPA SRS List Classificationhttps://sor.epa.gov/sor_internet/registry/substreg/LandingPage.do
- MolGenieMolGenie Organic Chemistry Ontologyhttps://github.com/MolGenie/ontology/
- PATENTSCOPE (WIPO)SID 403383125https://pubchem.ncbi.nlm.nih.gov/substance/403383125
- NCBI