71228284 -OEChem-04252416502D 88 90 0 1 0 0 0 0 0999 V2000 10.2649 2.4594 0.0000 S 0 0 0 0 0 0 0 0 0 0 0 0 5.2181 -2.8770 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 4.3520 -2.3770 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.1288 1.8891 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.8520 -1.2430 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 6.0841 0.6230 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.2181 0.1230 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 8.7867 3.1175 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 3.4860 -0.8770 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 2.6200 0.6230 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 2.6200 -0.3770 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.4860 1.1230 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 4.3520 0.6230 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 4.3520 -1.3770 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 4.3520 -0.3770 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.6200 1.6230 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.6200 -1.3770 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.2181 -0.8770 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.2181 1.1230 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.0841 -3.3770 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.4860 2.1230 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.7181 -3.7430 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.7181 -2.0110 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.4860 3.1230 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.2181 0.1230 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.9501 -3.8770 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.5841 -4.2430 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.5841 -2.5110 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.3520 3.6230 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.0841 1.6230 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 5.2181 2.1230 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.2181 3.1230 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.9501 2.1230 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.9501 3.1230 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.8162 1.6230 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.6822 2.1230 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.5957 1.7163 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.7648 3.3254 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.1716 4.2390 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 1.7700 0.6230 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 2.0094 -0.2693 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 2.4080 -0.9596 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 3.0875 1.5980 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.3520 1.2430 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.8890 -1.6870 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 2.4080 2.2056 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 2.0094 1.5154 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 2.3100 -0.8401 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 2.0831 -1.6870 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 2.9300 -1.9139 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 5.4301 -1.4596 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 5.8287 -0.7693 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 5.5281 0.5861 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 5.7550 1.4330 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.9081 1.6600 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 3.6981 1.5404 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.0966 2.2307 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.2365 2.4996 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.1811 -3.4330 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.4081 -4.2800 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 5.2550 -4.0530 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.2550 -2.3210 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.0281 -1.4740 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 5.1811 -1.7010 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 3.2740 3.7056 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 2.8754 3.0154 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.6401 -4.4139 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.4871 -4.1870 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.2601 -3.3400 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 5.0472 -3.9330 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 5.2741 -4.7800 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.1210 -4.5530 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.1210 -2.8210 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.8941 -1.9740 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.0472 -2.2010 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.3520 4.2430 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.6210 1.3130 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.6075 2.2307 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 5.0060 1.5404 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 5.7550 3.4330 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.5701 3.1230 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.9501 3.7430 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.3301 3.1230 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.8162 1.0030 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.7246 1.1098 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.7380 3.9868 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.4238 4.8054 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.6052 4.4912 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 1 37 1 0 0 0 0 1 38 1 0 0 0 0 2 3 1 0 0 0 0 2 20 1 0 0 0 0 2 22 1 0 0 0 0 2 23 1 0 0 0 0 14 3 1 6 0 0 0 12 4 1 6 0 0 0 4 58 1 0 0 0 0 5 15 2 0 0 0 0 6 25 1 0 0 0 0 6 30 1 0 0 0 0 7 25 2 0 0 0 0 8 36 1 0 0 0 0 8 38 2 0 0 0 0 9 11 1 0 0 0 0 9 14 1 0 0 0 0 9 15 1 0 0 0 0 9 17 1 6 0 0 0 10 11 1 0 0 0 0 10 12 1 0 0 0 0 10 16 1 0 0 0 0 10 40 1 6 0 0 0 11 41 1 0 0 0 0 11 42 1 0 0 0 0 12 13 1 0 0 0 0 12 43 1 0 0 0 0 13 15 1 0 0 0 0 13 19 1 1 0 0 0 13 44 1 0 0 0 0 14 18 1 0 0 0 0 14 45 1 0 0 0 0 16 21 1 0 0 0 0 16 46 1 0 0 0 0 16 47 1 0 0 0 0 17 48 1 0 0 0 0 17 49 1 0 0 0 0 17 50 1 0 0 0 0 18 25 1 0 0 0 0 18 51 1 0 0 0 0 18 52 1 0 0 0 0 19 53 1 0 0 0 0 19 54 1 0 0 0 0 19 55 1 0 0 0 0 20 26 1 0 0 0 0 20 27 1 0 0 0 0 20 28 1 0 0 0 0 21 24 1 0 0 0 0 21 56 1 0 0 0 0 21 57 1 0 0 0 0 22 59 1 0 0 0 0 22 60 1 0 0 0 0 22 61 1 0 0 0 0 23 62 1 0 0 0 0 23 63 1 0 0 0 0 23 64 1 0 0 0 0 24 29 1 0 0 0 0 24 65 1 0 0 0 0 24 66 1 0 0 0 0 26 67 1 0 0 0 0 26 68 1 0 0 0 0 26 69 1 0 0 0 0 27 70 1 0 0 0 0 27 71 1 0 0 0 0 27 72 1 0 0 0 0 28 73 1 0 0 0 0 28 74 1 0 0 0 0 28 75 1 0 0 0 0 29 32 2 0 0 0 0 29 76 1 0 0 0 0 30 31 1 0 0 0 0 30 33 1 1 0 0 0 30 77 1 0 0 0 0 31 32 1 0 0 0 0 31 78 1 0 0 0 0 31 79 1 0 0 0 0 32 80 1 0 0 0 0 33 34 1 0 0 0 0 33 35 2 0 0 0 0 34 81 1 0 0 0 0 34 82 1 0 0 0 0 34 83 1 0 0 0 0 35 36 1 0 0 0 0 35 84 1 0 0 0 0 36 37 2 0 0 0 0 37 85 1 0 0 0 0 38 39 1 0 0 0 0 39 86 1 0 0 0 0 39 87 1 0 0 0 0 39 88 1 0 0 0 0 M END > 71228284 > 1 > 944 > 7 > 1 > 5 > AAADcfB6OAhAAAAAAAAAAAAAAAAAAWAAAAAwAAAAAAAAAAABgAAAHhQACEAADxyl9gLiiRIIFgmsA6TyTACC8KBhCjgIiBUQIBgIFBagIQACUAAF4ACooAeI7uTvAAAAAAAAAABAAAQAABAAAAAAAAAAAA== > (1R,2S,6S,8Z,13R,14S,15R)-2-[tert-butyl(dimethyl)silyl]oxy-14-hydroxy-1,15-dimethyl-6-[(E)-1-methyl-2-(2-methylthiazol-4-yl)vinyl]-5-oxabicyclo[11.3.1]heptadec-8-ene-4,16-dione > (1R,2S,6S,8Z,13R,14S,15R)-2-[tert-butyl(dimethyl)silyl]oxy-14-hydroxy-1,15-dimethyl-6-[(E)-1-(2-methyl-4-thiazolyl)prop-1-en-2-yl]-5-oxabicyclo[11.3.1]heptadec-8-ene-4,16-dione > (1R,2S,6S,8Z,13R,14S,15R)-2-[tert-butyl(dimethyl)silyl]oxy-14-hydroxy-1,15-dimethyl-6-[(E)-1-(2-methyl-1,3-thiazol-4-yl)prop-1-en-2-yl]-5-oxabicyclo[11.3.1]heptadec-8-ene-4,16-dione > (1R,2S,6S,8Z,13R,14S,15R)-2-[tert-butyl(dimethyl)silyl]oxy-14-hydroxy-1,15-dimethyl-6-[(E)-1-(2-methyl-1,3-thiazol-4-yl)prop-1-en-2-yl]-5-oxabicyclo[11.3.1]heptadec-8-ene-4,16-dione > (1R,2S,6S,8Z,13R,14S,15R)-2-[tert-butyl(dimethyl)silyl]oxy-1,15-dimethyl-6-[(E)-1-(2-methyl-1,3-thiazol-4-yl)prop-1-en-2-yl]-14-oxidanyl-5-oxabicyclo[11.3.1]heptadec-8-ene-4,16-dione > (1R,2S,6S,8Z,13R,14S,15R)-2-[tert-butyl(dimethyl)silyl]oxy-14-hydroxy-1,15-dimethyl-6-[(E)-1-methyl-2-(2-methylthiazol-4-yl)vinyl]-5-oxabicyclo[11.3.1]heptadec-8-ene-4,16-quinone > InChI=1S/C31H49NO5SSi/c1-20(16-24-19-38-22(3)32-24)25-15-13-11-10-12-14-23-18-31(7,29(35)21(2)28(23)34)26(17-27(33)36-25)37-39(8,9)30(4,5)6/h11,13,16,19,21,23,25-26,28,34H,10,12,14-15,17-18H2,1-9H3/b13-11-,20-16+/t21-,23-,25+,26+,28-,31-/m1/s1 > NAHNARHVVJGLHK-SQXLZBDQSA-N > 575.31007137 > C31H49NO5SSi > 575.9 > CC1C(C2CCCC=CCC(OC(=O)CC(C(C2)(C1=O)C)O[Si](C)(C)C(C)(C)C)C(=CC3=CSC(=N3)C)C)O > C[C@@H]1[C@H]([C@@H]2CCC/C=C\C[C@H](OC(=O)C[C@@H]([C@@](C2)(C1=O)C)O[Si](C)(C)C(C)(C)C)/C(=C/C3=CSC(=N3)C)/C)O > 114 > 575.31007137 > 0 > 39 > 6 > 0 > 2 > 0 > 0 > 1 > -1 > 1 5 255 > 1 37 8 1 38 8 10 40 6 13 19 5 14 3 6 30 33 5 36 37 8 12 4 6 8 36 8 8 38 8 9 17 6 $$$$