59782009 -OEChem-05112413222D 78 81 0 1 0 0 0 0 0999 V2000 8.0622 -1.3240 0.0000 S 0 0 0 0 0 0 0 0 0 0 0 0 5.4641 0.1760 0.0000 S 0 0 0 0 0 0 0 0 0 0 0 0 14.6395 -0.8531 0.0000 S 0 0 0 0 0 0 0 0 0 0 0 0 7.1962 3.1760 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 16.6076 -1.5521 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 10.6421 0.8887 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 7.1962 2.1760 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 8.9282 2.1760 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 11.8694 -0.3145 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 11.0870 -3.2106 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 3.7320 3.1760 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 2.0000 2.1760 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 8.9282 0.1760 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 10.6421 -1.5367 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 15.8292 -2.1799 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 12.0534 -2.9538 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 3.7320 0.1760 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 14.0566 -2.3625 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 4.5981 1.6760 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 2.8660 0.6760 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 8.9282 -0.8240 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 9.9365 -0.8281 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 9.9365 0.1802 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.0622 0.6760 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.1962 0.1760 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.1962 -0.8240 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.3301 0.6760 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.0622 1.6760 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 11.6086 -1.2798 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 12.3142 -1.9884 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.1962 4.1760 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.1962 3.1760 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.1962 3.1760 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 13.2807 -1.7316 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.5981 0.6760 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 14.8963 -1.8196 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 13.6410 -0.7987 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 17.3861 -0.9244 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 17.2353 -2.3306 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 15.9799 -0.7737 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.7320 -0.8240 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.7320 2.1760 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8660 1.6760 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.8262 -4.1760 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.1465 -1.6455 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.6975 -1.4002 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.5856 -0.7163 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.9841 -1.4066 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.4804 -2.1352 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.7287 1.1510 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 5.9316 1.1510 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.8162 4.1760 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.1962 4.7960 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.5762 4.1760 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.1962 3.7960 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 5.5762 3.1760 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.1962 2.5560 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 8.1962 2.5560 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 8.8162 3.1760 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 8.1962 3.7960 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 15.9249 -2.7924 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 13.3044 -0.2781 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 17.7752 -1.4070 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 17.8687 -0.5352 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 16.9969 -0.4418 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 16.7527 -2.7198 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 17.6245 -2.8132 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 17.7180 -1.9414 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 16.4625 -0.3845 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 15.5907 -0.2911 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 15.4973 -1.1629 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 2.3291 0.3660 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 3.1120 -0.8240 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 3.7320 -1.4440 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.3520 -0.8240 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.2276 -4.0143 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.6645 -4.7746 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 11.4247 -4.3377 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 1 21 1 0 0 0 0 1 26 1 0 0 0 0 2 27 1 0 0 0 0 2 35 1 0 0 0 0 3 36 1 0 0 0 0 3 37 1 0 0 0 0 4 7 1 0 0 0 0 4 31 1 0 0 0 0 4 32 1 0 0 0 0 4 33 1 0 0 0 0 5 15 1 0 0 0 0 5 38 1 0 0 0 0 5 39 1 0 0 0 0 5 40 1 0 0 0 0 6 23 2 0 0 0 0 7 28 1 0 0 0 0 8 28 2 0 0 0 0 9 29 2 0 0 0 0 10 16 1 0 0 0 0 10 44 1 0 0 0 0 11 42 2 0 0 0 0 12 43 2 0 0 0 0 13 21 1 0 0 0 0 13 23 1 0 0 0 0 13 24 1 0 0 0 0 22 14 1 1 0 0 0 14 29 1 0 0 0 0 14 49 1 0 0 0 0 15 36 1 0 0 0 0 15 61 1 0 0 0 0 16 30 2 0 0 0 0 17 20 1 0 0 0 0 17 35 1 0 0 0 0 17 41 1 0 0 0 0 18 34 1 0 0 0 0 18 36 2 0 0 0 0 19 35 2 0 0 0 0 19 42 1 0 0 0 0 20 43 1 0 0 0 0 20 72 1 0 0 0 0 21 22 1 0 0 0 0 21 45 1 6 0 0 0 22 23 1 0 0 0 0 22 46 1 0 0 0 0 24 25 2 0 0 0 0 24 28 1 0 0 0 0 25 26 1 0 0 0 0 25 27 1 0 0 0 0 26 47 1 0 0 0 0 26 48 1 0 0 0 0 27 50 1 0 0 0 0 27 51 1 0 0 0 0 29 30 1 0 0 0 0 30 34 1 0 0 0 0 31 52 1 0 0 0 0 31 53 1 0 0 0 0 31 54 1 0 0 0 0 32 55 1 0 0 0 0 32 56 1 0 0 0 0 32 57 1 0 0 0 0 33 58 1 0 0 0 0 33 59 1 0 0 0 0 33 60 1 0 0 0 0 34 37 2 0 0 0 0 37 62 1 0 0 0 0 38 63 1 0 0 0 0 38 64 1 0 0 0 0 38 65 1 0 0 0 0 39 66 1 0 0 0 0 39 67 1 0 0 0 0 39 68 1 0 0 0 0 40 69 1 0 0 0 0 40 70 1 0 0 0 0 40 71 1 0 0 0 0 41 73 1 0 0 0 0 41 74 1 0 0 0 0 41 75 1 0 0 0 0 42 43 1 0 0 0 0 44 76 1 0 0 0 0 44 77 1 0 0 0 0 44 78 1 0 0 0 0 M END > 59782009 > 1 > 1330 > 13 > 3 > 12 > AAADcfB7+AxgAAAAAAAAAAAAAABYAWAAAAAgQAAAAAAQAAABgAAAHhQdAEAADCjF1gbjmRP6EAmsAwXyfAAA8KlhCjkTKJW4IFiCZJggxCEUEAAAFgKwASAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAAA== > trimethylsilyl (6R,7R)-7-[[(2Z)-2-methoxyimino-2-[2-(trimethylsilylamino)thiazol-4-yl]acetyl]amino]-3-[(2-methyl-5,6-dioxo-1H-1,2,4-triazin-3-yl)sulfanylmethyl]-8-oxo-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylate > (6R,7R)-7-[[(2Z)-2-methoxyimino-1-oxo-2-[2-(trimethylsilylamino)-4-thiazolyl]ethyl]amino]-3-[[(2-methyl-5,6-dioxo-1H-1,2,4-triazin-3-yl)thio]methyl]-8-oxo-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylic acid trimethylsilyl ester > trimethylsilyl (6R,7R)-7-[[(2Z)-2-methoxyimino-2-[2-(trimethylsilylamino)-1,3-thiazol-4-yl]acetyl]amino]-3-[(2-methyl-5,6-dioxo-1H-1,2,4-triazin-3-yl)sulfanylmethyl]-8-oxo-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylate > trimethylsilyl (6R,7R)-7-[[(2Z)-2-methoxyimino-2-[2-(trimethylsilylamino)-1,3-thiazol-4-yl]acetyl]amino]-3-[(2-methyl-5,6-dioxo-1H-1,2,4-triazin-3-yl)sulfanylmethyl]-8-oxo-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylate > trimethylsilyl (6R,7R)-7-[[(2Z)-2-methoxyimino-2-[2-(trimethylsilylamino)-1,3-thiazol-4-yl]ethanoyl]amino]-3-[[2-methyl-5,6-bis(oxidanylidene)-1H-1,2,4-triazin-3-yl]sulfanylmethyl]-8-oxidanylidene-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylate > (6R,7R)-3-[[(5,6-diketo-2-methyl-1H-1,2,4-triazin-3-yl)thio]methyl]-8-keto-7-[[(2Z)-2-methyloximino-2-[2-(trimethylsilylamino)thiazol-4-yl]acetyl]amino]-5-thia-1-azabicyclo[4.2.0]oct-2-ene-2-carboxylic acid trimethylsilyl ester > InChI=1S/C24H34N8O7S3Si2/c1-31-24(27-18(34)19(35)28-31)42-10-12-9-40-21-15(20(36)32(21)16(12)22(37)39-44(6,7)8)26-17(33)14(29-38-2)13-11-41-23(25-13)30-43(3,4)5/h11,15,21H,9-10H2,1-8H3,(H,25,30)(H,26,33)(H,28,35)/b29-14-/t15-,21-/m1/s1 > IYKLTNMMPPEKTM-LECZYUNPSA-N > 698.12511204 > C24H34N8O7S3Si2 > 698.9 > CN1C(=NC(=O)C(=O)N1)SCC2=C(N3C(C(C3=O)NC(=O)C(=NOC)C4=CSC(=N4)N[Si](C)(C)C)SC2)C(=O)O[Si](C)(C)C > CN1C(=NC(=O)C(=O)N1)SCC2=C(N3[C@@H]([C@@H](C3=O)NC(=O)/C(=N\OC)/C4=CSC(=N4)N[Si](C)(C)C)SC2)C(=O)O[Si](C)(C)C > 263 > 698.12511204 > 0 > 44 > 2 > 0 > 1 > 0 > 0 > 1 > -1 > 1 5 255 > 22 14 5 17 20 8 17 35 8 18 34 8 18 36 8 19 35 8 19 42 8 20 43 8 21 45 6 3 36 8 3 37 8 34 37 8 42 43 8 $$$$