24884077 -OEChem-04182400052D 89 93 0 1 0 0 0 0 0999 V2000 6.6969 -2.8154 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 9.1891 0.9037 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 8.8746 -1.4129 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 5.5162 1.3189 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 6.0117 -2.0871 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 8.4608 0.2183 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 7.9012 -1.6421 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 7.5484 2.2163 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.4394 2.5473 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 6.1653 2.4018 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.4481 0.4307 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 5.6621 -0.4150 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 4.7500 -0.4365 0.0000 C 0 0 3 0 0 0 0 0 0 0 0 0 5.9251 0.4591 0.0000 C 0 0 3 0 0 0 0 0 0 0 0 0 5.1763 0.9799 0.0000 C 0 0 3 0 0 0 0 0 0 0 0 0 6.8424 0.6751 0.0000 C 0 0 3 0 0 0 0 0 0 0 0 0 3.7521 -0.4017 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.2999 -1.1295 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 3.5812 0.7353 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.2598 -1.2130 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.6992 -0.6643 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 7.4875 -0.0111 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 7.2160 -0.9138 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 3.3475 -1.3143 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.8036 0.2483 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.1072 1.3189 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.8258 0.8563 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.2603 1.9764 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0000 0.8434 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.3821 -3.5438 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.9685 -3.5006 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.4253 -2.1303 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.5234 3.5438 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.8744 0.1755 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.9173 1.5890 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.5037 1.6319 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.1038 -2.3863 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.6454 -0.4395 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.8480 -1.1837 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.0558 -0.9759 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.0411 1.0681 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.6335 1.2795 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 3.7092 -1.0203 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.3272 -0.6333 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 5.6946 -1.2637 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 3.9118 1.2598 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 3.1434 1.1743 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.1892 -1.8290 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.8446 -1.4190 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 1.8965 -0.9438 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.9124 -0.4626 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.0374 -1.5075 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 2.8220 -1.6434 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 3.5514 -1.8998 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.9382 0.2465 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 8.4356 0.9686 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.7135 1.4660 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 2.0704 1.4594 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 1.4313 0.5964 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.9305 -3.9686 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.8069 -3.9954 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.8337 -3.1190 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 5.5437 -3.0491 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 5.5170 -3.9255 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.3934 -3.9522 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.8501 -2.5818 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.8768 -1.7054 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.0004 -1.6787 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 5.1412 3.4917 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.5755 4.1616 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 3.9056 3.5959 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.4229 -0.2495 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.2993 -0.2760 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.3259 0.6004 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.3422 1.1375 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.3688 2.0139 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.4924 2.0405 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 8.9552 2.0568 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 8.0788 2.0834 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 8.0522 1.2070 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 8.5003 -2.5284 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.2459 -2.9898 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.7073 -2.2442 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.2489 -0.2974 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 8.5033 0.1640 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 8.0419 -0.5816 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.9901 -1.7872 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.4515 -1.0416 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.7059 -0.5802 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 1 5 1 0 0 0 0 1 30 1 0 0 0 0 1 31 1 0 0 0 0 1 32 1 0 0 0 0 2 6 1 0 0 0 0 2 34 1 0 0 0 0 2 35 1 0 0 0 0 2 36 1 0 0 0 0 3 7 1 0 0 0 0 3 37 1 0 0 0 0 3 38 1 0 0 0 0 3 39 1 0 0 0 0 12 4 1 6 0 0 0 4 26 1 0 0 0 0 18 5 1 1 0 0 0 22 6 1 1 0 0 0 23 7 1 1 0 0 0 8 26 2 0 0 0 0 9 28 1 0 0 0 0 9 33 1 0 0 0 0 10 28 2 0 0 0 0 11 13 1 0 0 0 0 11 15 1 6 0 0 0 11 17 1 0 0 0 0 11 19 1 0 0 0 0 12 13 1 0 0 0 0 12 14 1 0 0 0 0 12 18 1 0 0 0 0 13 20 1 0 0 0 0 13 40 1 0 0 0 0 14 15 1 0 0 0 0 14 16 1 0 0 0 0 14 41 1 0 0 0 0 15 28 1 0 0 0 0 15 42 1 0 0 0 0 16 22 1 0 0 0 0 16 26 1 0 0 0 0 16 27 1 0 0 0 0 17 21 1 0 0 0 0 17 43 1 0 0 0 0 17 44 1 0 0 0 0 18 23 1 0 0 0 0 18 45 1 0 0 0 0 19 25 1 0 0 0 0 19 46 1 0 0 0 0 19 47 1 0 0 0 0 20 24 1 0 0 0 0 20 48 1 0 0 0 0 20 49 1 0 0 0 0 21 24 1 0 0 0 0 21 25 1 0 0 0 0 21 50 1 6 0 0 0 22 23 1 0 0 0 0 22 51 1 0 0 0 0 23 52 1 0 0 0 0 24 53 1 0 0 0 0 24 54 1 0 0 0 0 25 29 2 0 0 0 0 27 55 1 0 0 0 0 27 56 1 0 0 0 0 27 57 1 0 0 0 0 29 58 1 0 0 0 0 29 59 1 0 0 0 0 30 60 1 0 0 0 0 30 61 1 0 0 0 0 30 62 1 0 0 0 0 31 63 1 0 0 0 0 31 64 1 0 0 0 0 31 65 1 0 0 0 0 32 66 1 0 0 0 0 32 67 1 0 0 0 0 32 68 1 0 0 0 0 33 69 1 0 0 0 0 33 70 1 0 0 0 0 33 71 1 0 0 0 0 34 72 1 0 0 0 0 34 73 1 0 0 0 0 34 74 1 0 0 0 0 35 75 1 0 0 0 0 35 76 1 0 0 0 0 35 77 1 0 0 0 0 36 78 1 0 0 0 0 36 79 1 0 0 0 0 36 80 1 0 0 0 0 37 81 1 0 0 0 0 37 82 1 0 0 0 0 37 83 1 0 0 0 0 38 84 1 0 0 0 0 38 85 1 0 0 0 0 38 86 1 0 0 0 0 39 87 1 0 0 0 0 39 88 1 0 0 0 0 39 89 1 0 0 0 0 M END > 24884077 > 1 > 1070 > 7 > 0 > 8 > AAADcfB4OAwAAAAAAAAAAAAAAAAAAaMEAAAwYAAABogSAGDAAAAAGhAAAEAAD1SggAJCCAAABAGIAgDSCAAAAAAgAAAAAAEAAAgBABYAAQACAAAFoAACAAHK7vzPgAAAAAAAAADCAAYQADCAAYAADAAAAA== > methyl (1R,5R,8R,12R,13R,14R)-11-methyl-6-methylene-16-oxo-12,13,14-tris(trimethylsilyloxy)-15-oxapentacyclo[9.3.2.15,8.01,10.02,8]heptadecane-9-carboxylate > (1R,5R,8R,12R,13R,14R)-11-methyl-6-methylene-16-oxo-12,13,14-tris(trimethylsilyloxy)-15-oxapentacyclo[9.3.2.15,8.01,10.02,8]heptadecane-9-carboxylic acid methyl ester > methyl (1R,5R,8R,12R,13R,14R)-11-methyl-6-methylidene-16-oxo-12,13,14-tris(trimethylsilyloxy)-15-oxapentacyclo[9.3.2.15,8.01,10.02,8]heptadecane-9-carboxylate > methyl (1R,5R,8R,12R,13R,14R)-11-methyl-6-methylidene-16-oxo-12,13,14-tris(trimethylsilyloxy)-15-oxapentacyclo[9.3.2.15,8.01,10.02,8]heptadecane-9-carboxylate > methyl (1R,5R,8R,12R,13R,14R)-11-methyl-6-methylidene-16-oxidanylidene-12,13,14-tris(trimethylsilyloxy)-15-oxapentacyclo[9.3.2.15,8.01,10.02,8]heptadecane-9-carboxylate > (1R,5R,8R,12R,13R,14R)-16-keto-11-methyl-6-methylene-12,13,14-tris(trimethylsilyloxy)-15-oxapentacyclo[9.3.2.15,8.01,10.02,8]heptadecane-9-carboxylic acid methyl ester > InChI=1S/C29H50O7Si3/c1-17-15-28-16-18(17)13-14-19(28)29-22(20(28)25(30)32-3)27(2,26(31)33-29)23(35-38(7,8)9)21(34-37(4,5)6)24(29)36-39(10,11)12/h18-24H,1,13-16H2,2-12H3/t18-,19?,20?,21-,22?,23+,24-,27?,28+,29-/m1/s1 > FNTIFNGWHIDZGQ-KWCMPHIGSA-N > 594.28643353 > C29H50O7Si3 > 595.0 > CC12C3C(C45CC(CCC4C3(C(C(C1O[Si](C)(C)C)O[Si](C)(C)C)O[Si](C)(C)C)OC2=O)C(=C)C5)C(=O)OC > CC12[C@H]([C@H]([C@H]([C@@]3(C1C([C@]45C3CC[C@H](C4)C(=C)C5)C(=O)OC)OC2=O)O[Si](C)(C)C)O[Si](C)(C)C)O[Si](C)(C)C > 80.3 > 594.28643353 > 0 > 39 > 6 > 4 > 0 > 0 > 0 > 1 > -1 > 1 5 255 > 11 15 6 13 20 3 14 15 3 15 28 3 16 27 3 21 50 6 12 4 6 18 5 5 22 6 5 23 7 5 $$$$