16760141 -OEChem-05072423032D 99103 0 1 0 0 0 0 0999 V2000 8.4692 -0.2874 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 8.4692 -1.2874 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.6731 5.2874 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 5.8711 1.2126 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.1390 3.2126 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 2.5587 4.5004 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 6.8711 2.2126 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 5.8711 -3.7874 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 5.8711 -2.7874 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 5.0050 3.7126 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 7.6031 -0.7874 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 4.2680 4.3796 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 6.7371 -0.2874 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.7371 0.7126 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 5.0050 2.7126 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 7.6031 1.2126 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.4692 0.7126 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 6.7371 -1.2874 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.3848 3.9369 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 5.8711 4.2126 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.4692 -2.2874 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 7.6031 -2.7874 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 6.7371 -2.2874 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.0831 2.3573 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.2948 2.9529 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.6619 5.1844 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.8711 2.2126 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.3352 1.2126 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.3352 -2.7874 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.6031 -3.7874 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.7371 3.7126 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.3802 2.5486 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.3352 2.2126 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.3352 -3.7874 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.2012 -2.2874 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.6031 4.2126 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.2012 2.7126 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.2012 3.7126 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.3352 4.2126 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 10.2012 -4.2874 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.4692 3.7126 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 11.0672 2.2126 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.3352 5.2126 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.2012 -5.2874 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 11.0672 -3.7874 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.0050 -4.2874 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.6536 4.9670 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.1265 -0.1798 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.5250 -0.8700 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.0010 0.2876 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 5.0050 1.8626 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 8.0016 1.6875 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.2046 1.6875 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.2053 0.2876 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.5250 -0.7048 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.1265 -1.3951 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 3.4263 4.5555 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.0061 -1.9774 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 8.1401 -3.0974 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 3.9968 1.7433 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.2783 5.2504 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 5.6610 5.8044 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.5472 0.6300 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.9458 1.3202 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.0314 3.8232 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.9831 -3.7874 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.6031 -4.4074 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 8.2231 -3.7874 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.0472 3.1757 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 2.1295 3.1156 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 1.8131 2.2979 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 2.6309 1.9815 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 2.0000 4.2315 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 8.7982 2.5226 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 8.7982 -4.0974 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.5112 -2.8244 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.7381 -1.9774 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.8912 -1.7505 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.6031 4.8326 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.8118 3.6049 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.4132 4.2952 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.8721 4.5226 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.6643 -4.5974 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 8.4692 3.0926 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.7572 1.6756 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 11.6042 1.9026 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 11.3772 2.7495 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.9552 5.2126 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.3352 5.8326 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 8.7152 5.2126 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.5812 -5.2874 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.2012 -5.9074 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.8212 -5.2874 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 11.3772 -4.3244 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 11.6042 -3.4774 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.7572 -3.2505 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.6950 -3.7505 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.4681 -4.5974 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 5.3150 -4.8244 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 1 11 1 0 0 0 0 1 17 1 0 0 0 0 11 2 1 6 0 0 0 2 21 1 0 0 0 0 3 12 1 0 0 0 0 3 26 1 0 0 0 0 4 14 1 0 0 0 0 4 27 1 0 0 0 0 10 5 1 6 0 0 0 5 65 1 0 0 0 0 19 6 1 1 0 0 0 6 73 1 0 0 0 0 7 27 2 0 0 0 0 8 9 1 0 0 0 0 8 46 1 0 0 0 0 9 23 2 0 0 0 0 10 12 1 0 0 0 0 10 15 1 0 0 0 0 10 20 1 0 0 0 0 11 13 1 0 0 0 0 11 18 1 0 0 0 0 12 19 1 0 0 0 0 12 47 1 6 0 0 0 13 14 1 0 0 0 0 13 48 1 0 0 0 0 13 49 1 0 0 0 0 14 16 1 0 0 0 0 14 50 1 6 0 0 0 15 24 1 0 0 0 0 15 27 1 0 0 0 0 15 51 1 1 0 0 0 16 17 1 0 0 0 0 16 52 1 0 0 0 0 16 53 1 0 0 0 0 17 28 1 0 0 0 0 17 54 1 6 0 0 0 18 23 1 0 0 0 0 18 55 1 0 0 0 0 18 56 1 0 0 0 0 19 25 1 0 0 0 0 19 57 1 0 0 0 0 20 26 1 0 0 0 0 20 31 2 0 0 0 0 21 22 1 0 0 0 0 21 29 1 6 0 0 0 21 58 1 0 0 0 0 22 23 1 0 0 0 0 22 30 1 1 0 0 0 22 59 1 0 0 0 0 24 25 2 0 0 0 0 24 60 1 0 0 0 0 25 32 1 0 0 0 0 26 61 1 0 0 0 0 26 62 1 0 0 0 0 28 33 1 0 0 0 0 28 63 1 0 0 0 0 28 64 1 0 0 0 0 29 34 2 0 0 0 0 29 35 1 0 0 0 0 30 66 1 0 0 0 0 30 67 1 0 0 0 0 30 68 1 0 0 0 0 31 36 1 0 0 0 0 31 69 1 0 0 0 0 32 70 1 0 0 0 0 32 71 1 0 0 0 0 32 72 1 0 0 0 0 33 37 2 0 0 0 0 33 74 1 0 0 0 0 34 40 1 0 0 0 0 34 75 1 0 0 0 0 35 76 1 0 0 0 0 35 77 1 0 0 0 0 35 78 1 0 0 0 0 36 41 2 0 0 0 0 36 79 1 0 0 0 0 37 38 1 0 0 0 0 37 42 1 0 0 0 0 38 39 1 0 0 0 0 38 80 1 0 0 0 0 38 81 1 0 0 0 0 39 41 1 0 0 0 0 39 43 1 6 0 0 0 39 82 1 0 0 0 0 40 44 1 0 0 0 0 40 45 1 0 0 0 0 40 83 1 0 0 0 0 41 84 1 0 0 0 0 42 85 1 0 0 0 0 42 86 1 0 0 0 0 42 87 1 0 0 0 0 43 88 1 0 0 0 0 43 89 1 0 0 0 0 43 90 1 0 0 0 0 44 91 1 0 0 0 0 44 92 1 0 0 0 0 44 93 1 0 0 0 0 45 94 1 0 0 0 0 45 95 1 0 0 0 0 45 96 1 0 0 0 0 46 97 1 0 0 0 0 46 98 1 0 0 0 0 46 99 1 0 0 0 0 M END > 16760141 > 1 > 1340 > 9 > 2 > 3 > AAADcfB+PAAAAAAAAAAAAAAAAAAAASAAAAAkSIAAAAAAAEAAAAAAHgAECAAADVyhgAICCAAQBgCoAyDyCAAAAAAgAAAICAEwAAgZFBYAIQAiUAAF4AAPsAPK7OzOgAAAAAAAAAAAAAAAAAAAAAAAAAAAAA== > (1R,4S,4'Z,5'S,6R,6'S,8R,10E,13R,14E,16E,20R,21R,24S)-6'-[(E)-1,3-dimethylbut-1-enyl]-21,24-dihydroxy-4'-methoxyimino-5',11,13,22-tetramethyl-spiro[3,7,19-trioxatetracyclo[15.6.1.14,8.020,24]pentacosa-10,14,16,22-tetraene-6,2'-tetrahydropyran]-2-one > (1R,4S,4'Z,5'S,6R,6'S,8R,10E,13R,14E,16E,20R,21R,24S)-21,24-dihydroxy-4'-methoxyimino-5',11,13,22-tetramethyl-6'-[(E)-4-methylpent-2-en-2-yl]-2-spiro[3,7,19-trioxatetracyclo[15.6.1.14,8.020,24]pentacosa-10,14,16,22-tetraene-6,2'-oxane]one > (1R,4S,4'Z,5'S,6R,6'S,8R,10E,13R,14E,16E,20R,21R,24S)-21,24-dihydroxy-4'-methoxyimino-5',11,13,22-tetramethyl-6'-[(E)-4-methylpent-2-en-2-yl]spiro[3,7,19-trioxatetracyclo[15.6.1.14,8.020,24]pentacosa-10,14,16,22-tetraene-6,2'-oxane]-2-one > (1R,4S,4'Z,5'S,6R,6'S,8R,10E,13R,14E,16E,20R,21R,24S)-21,24-dihydroxy-4'-methoxyimino-5',11,13,22-tetramethyl-6'-[(E)-4-methylpent-2-en-2-yl]spiro[3,7,19-trioxatetracyclo[15.6.1.14,8.020,24]pentacosa-10,14,16,22-tetraene-6,2'-oxane]-2-one > (1R,4S,4'Z,5'S,6R,6'S,8R,10E,13R,14E,16E,20R,21R,24S)-4'-methoxyimino-5',11,13,22-tetramethyl-6'-[(E)-4-methylpent-2-en-2-yl]-21,24-bis(oxidanyl)spiro[3,7,19-trioxatetracyclo[15.6.1.14,8.020,24]pentacosa-10,14,16,22-tetraene-6,2'-oxane]-2-one > (1R,4S,4'Z,5'S,6R,6'S,8R,10E,13R,14E,16E,20R,21R,24S)-6'-[(E)-1,3-dimethylbut-1-enyl]-21,24-dihydroxy-5',11,13,22-tetramethyl-4'-methyloximino-spiro[3,7,19-trioxatetracyclo[15.6.1.14,8.020,24]pentacosa-10,14,16,22-tetraene-6,2'-tetrahydropyran]-2-one > InChI=1S/C37H53NO8/c1-21(2)14-25(6)33-26(7)31(38-42-8)19-36(46-33)18-29-17-28(45-36)13-12-23(4)15-22(3)10-9-11-27-20-43-34-32(39)24(5)16-30(35(40)44-29)37(27,34)41/h9-12,14,16,21-22,26,28-30,32-34,39,41H,13,15,17-20H2,1-8H3/b10-9+,23-12+,25-14+,27-11+,38-31-/t22-,26-,28+,29-,30-,32+,33+,34+,36-,37+/m0/s1 > YZBLFMPOMVTDJY-CBYMMZEQSA-N > 4.3 > 639.37711765 > C37H53NO8 > 639.8 > CC1CC(=CCC2CC(CC3(O2)CC(=NOC)C(C(O3)C(=CC(C)C)C)C)OC(=O)C4C=C(C(C5C4(C(=CC=C1)CO5)O)O)C)C > C[C@@H]\1C/C(=C/C[C@@H]2C[C@@H](C[C@@]3(O2)C/C(=N/OC)/[C@@H]([C@H](O3)/C(=C/C(C)C)/C)C)OC(=O)[C@@H]4C=C([C@H]([C@@H]5[C@]4(/C(=C/C=C1)/CO5)O)O)C)/C > 116 > 639.37711765 > 0 > 46 > 10 > 0 > 5 > 0 > 0 > 1 > -1 > 1 5 255 > 12 47 6 14 50 6 15 51 5 17 54 6 11 2 6 21 29 6 22 30 5 39 43 6 10 5 6 19 6 5 $$$$