10952576 -OEChem-05122404512D 107110 0 1 0 0 0 0 0999 V2000 8.5034 -2.2464 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 11.0185 0.3646 0.0000 Si 0 0 0 0 0 0 0 0 0 0 0 0 5.7583 2.9480 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 5.9772 0.0335 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 8.4511 -1.2478 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 2.5592 -1.0643 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 10.0809 0.0171 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 3.9951 -2.0328 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 5.8263 -1.6920 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 11.2141 3.0591 0.0000 O 0 0 0 0 0 0 0 0 0 0 0 0 4.1160 -0.3050 0.0000 N 0 0 0 0 0 0 0 0 0 0 0 0 6.4949 1.9654 0.0000 N 0 0 3 0 0 0 0 0 0 0 0 0 5.0150 0.1338 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 4.1860 0.6930 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 6.2360 0.9994 0.0000 C 0 0 1 0 0 0 0 0 0 0 0 0 4.4616 1.6542 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.5077 0.2048 0.0000 C 0 0 2 0 0 0 0 0 0 0 0 0 8.2849 0.8341 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.9265 1.7677 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.5601 -0.7938 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 3.5568 -1.1341 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.3111 0.6553 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.5695 2.5872 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.3998 -0.8728 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.9728 1.4598 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 8.5558 -3.2451 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.5020 -2.1941 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.5048 -2.2988 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.5995 2.4322 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 11.9562 0.7122 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 11.3661 -0.5730 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.6710 1.3023 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.7171 -3.7897 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.4468 -3.6991 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.0467 -3.0328 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 9.9560 -1.3031 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 7.0508 -3.1898 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 6.9602 -1.4601 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 2.0000 -1.8933 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.2258 3.2118 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 12.7260 0.0739 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 12.1240 1.6980 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 12.3519 -0.7409 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.7278 -1.3429 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 11.3092 2.0721 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 10.3234 2.2399 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 4.8301 -1.6048 0.0000 C 0 0 0 0 0 0 0 0 0 0 0 0 5.3876 -0.6302 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 3.4813 1.1683 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.4566 2.2742 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 3.8473 1.7380 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 8.0741 -0.0474 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.9447 -0.7183 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.3788 -1.3867 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 8.3406 3.1634 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.8383 -1.3112 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.9077 -0.5172 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.5848 1.3604 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 8.0033 -2.9636 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.1644 -1.6741 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.7863 -1.7464 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 12.5375 0.9276 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.7549 -0.4690 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.0896 1.0868 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.3794 -3.2698 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.1971 -4.1274 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 8.0548 -4.3097 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.1653 -4.2515 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.9992 -3.9806 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.7282 -3.1466 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.5267 -3.3705 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.3844 -3.5528 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.5667 -2.6951 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.5085 -1.5846 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.2375 -0.7507 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.4036 -1.0216 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.4984 -2.9083 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.7693 -3.7422 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.6032 -3.4713 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 7.4801 -1.1224 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.6225 -0.9401 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 6.4402 -1.7978 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 1.4860 -1.5466 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 1.6533 -2.4073 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 2.5140 -2.2400 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.0014 3.7897 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 12.3303 -0.4034 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 13.2033 -0.3218 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 13.1217 0.5512 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 12.7352 1.5939 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 12.2281 2.3092 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 11.5128 1.8020 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 12.2478 -1.3521 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 12.9631 -0.8450 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 12.4560 -0.1297 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.2505 -0.9471 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.3321 -1.8202 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 11.2051 -1.7386 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 11.7865 1.6764 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 11.7050 2.5494 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.8320 2.4678 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.9048 2.4554 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 10.1080 2.8213 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 9.7421 2.0245 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.8842 -0.9872 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.2125 -1.5508 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 4.7761 -2.2225 0.0000 H 0 0 0 0 0 0 0 0 0 0 0 0 1 5 1 0 0 0 0 1 26 1 0 0 0 0 1 27 1 0 0 0 0 1 28 1 0 0 0 0 2 7 1 0 0 0 0 2 30 1 0 0 0 0 2 31 1 0 0 0 0 2 32 1 0 0 0 0 3 12 1 0 0 0 0 3 15 1 0 0 0 0 15 4 1 1 0 0 0 4 24 1 0 0 0 0 5 20 1 0 0 0 0 6 21 1 0 0 0 0 6 39 1 0 0 0 0 7 22 1 0 0 0 0 8 21 2 0 0 0 0 9 24 1 0 0 0 0 9 47 1 0 0 0 0 10 40 2 0 0 0 0 11 13 1 0 0 0 0 11 14 1 0 0 0 0 11 21 1 0 0 0 0 12 16 1 0 0 0 0 12 19 1 0 0 0 0 13 14 1 0 0 0 0 13 15 1 0 0 0 0 13 48 1 6 0 0 0 14 16 1 0 0 0 0 14 49 1 6 0 0 0 15 17 1 0 0 0 0 16 50 1 0 0 0 0 16 51 1 0 0 0 0 17 18 1 0 0 0 0 17 20 1 6 0 0 0 17 52 1 0 0 0 0 18 19 2 0 0 0 0 18 22 1 0 0 0 0 19 23 1 0 0 0 0 20 53 1 0 0 0 0 20 54 1 0 0 0 0 22 25 2 0 0 0 0 23 29 2 0 0 0 0 23 55 1 0 0 0 0 24 56 1 0 0 0 0 24 57 1 0 0 0 0 25 29 1 0 0 0 0 25 58 1 0 0 0 0 26 33 1 0 0 0 0 26 34 1 0 0 0 0 26 59 1 0 0 0 0 27 35 1 0 0 0 0 27 36 1 0 0 0 0 27 60 1 0 0 0 0 28 37 1 0 0 0 0 28 38 1 0 0 0 0 28 61 1 0 0 0 0 29 40 1 0 0 0 0 30 41 1 0 0 0 0 30 42 1 0 0 0 0 30 62 1 0 0 0 0 31 43 1 0 0 0 0 31 44 1 0 0 0 0 31 63 1 0 0 0 0 32 45 1 0 0 0 0 32 46 1 0 0 0 0 32 64 1 0 0 0 0 33 65 1 0 0 0 0 33 66 1 0 0 0 0 33 67 1 0 0 0 0 34 68 1 0 0 0 0 34 69 1 0 0 0 0 34 70 1 0 0 0 0 35 71 1 0 0 0 0 35 72 1 0 0 0 0 35 73 1 0 0 0 0 36 74 1 0 0 0 0 36 75 1 0 0 0 0 36 76 1 0 0 0 0 37 77 1 0 0 0 0 37 78 1 0 0 0 0 37 79 1 0 0 0 0 38 80 1 0 0 0 0 38 81 1 0 0 0 0 38 82 1 0 0 0 0 39 83 1 0 0 0 0 39 84 1 0 0 0 0 39 85 1 0 0 0 0 40 86 1 0 0 0 0 41 87 1 0 0 0 0 41 88 1 0 0 0 0 41 89 1 0 0 0 0 42 90 1 0 0 0 0 42 91 1 0 0 0 0 42 92 1 0 0 0 0 43 93 1 0 0 0 0 43 94 1 0 0 0 0 43 95 1 0 0 0 0 44 96 1 0 0 0 0 44 97 1 0 0 0 0 44 98 1 0 0 0 0 45 99 1 0 0 0 0 45100 1 0 0 0 0 45101 1 0 0 0 0 46102 1 0 0 0 0 46103 1 0 0 0 0 46104 1 0 0 0 0 47105 1 0 0 0 0 47106 1 0 0 0 0 47107 1 0 0 0 0 M END > 10952576 > 1 > 1050 > 9 > 0 > 16 > AAADcfB/PAwAAAAAAAAAAAAAFgAAAAAAAAA8WIAABYAWAACxAAAAHhAEAEAADSzhuAdyzoMQBAGIAixS2ACCAAAlIgAgiAEObMgaZjLA1ZO1MQhnxhncyYf+2POOwAABQgAKAACAAAKEABQAAAAAAAAAAA== > methyl (8R,9R,10S,12S)-4-formyl-9-(methoxymethoxy)-6-triisopropylsilyloxy-8-(triisopropylsilyloxymethyl)-14-oxa-1,11-diazatetracyclo[7.4.1.02,7.010,12]tetradeca-2(7),3,5-triene-11-carboxylate > (8R,9R,10S,12S)-4-formyl-9-(methoxymethoxy)-6-tri(propan-2-yl)silyloxy-8-[tri(propan-2-yl)silyloxymethyl]-14-oxa-1,11-diazatetracyclo[7.4.1.02,7.010,12]tetradeca-2(7),3,5-triene-11-carboxylic acid methyl ester > methyl (8R,9R,10S,12S)-4-formyl-9-(methoxymethoxy)-6-tri(propan-2-yl)silyloxy-8-[tri(propan-2-yl)silyloxymethyl]-14-oxa-1,11-diazatetracyclo[7.4.1.02,7.010,12]tetradeca-2(7),3,5-triene-11-carboxylate > methyl (8R,9R,10S,12S)-4-formyl-9-(methoxymethoxy)-6-tri(propan-2-yl)silyloxy-8-[tri(propan-2-yl)silyloxymethyl]-14-oxa-1,11-diazatetracyclo[7.4.1.02,7.010,12]tetradeca-2(7),3,5-triene-11-carboxylate > methyl (8R,9R,10S,12S)-4-methanoyl-9-(methoxymethoxy)-6-tri(propan-2-yl)silyloxy-8-[tri(propan-2-yl)silyloxymethyl]-14-oxa-1,11-diazatetracyclo[7.4.1.02,7.010,12]tetradeca-2(7),3,5-triene-11-carboxylate > (8R,9R,10S,12S)-4-formyl-9-(methoxymethoxy)-6-triisopropylsilyloxy-8-(triisopropylsilyloxymethyl)-14-oxa-1,11-diazatetracyclo[7.4.1.02,7.010,12]tetradeca-2(7),3,5-triene-11-carboxylic acid methyl ester > InChI=1S/C35H60N2O8Si2/c1-21(2)46(22(3)4,23(5)6)43-19-28-32-29(15-27(18-38)16-31(32)44-47(24(7)8,25(9)10)26(11)12)36-17-30-33(37(30)34(39)41-14)35(28,45-36)42-20-40-13/h15-16,18,21-26,28,30,33H,17,19-20H2,1-14H3/t28-,30-,33-,35+,37?/m0/s1 > JEOVZHSQWXSLEM-ZUJOKWGISA-N > 692.38881995 > C35H60N2O8Si2 > 693.0 > CC(C)[Si](C(C)C)(C(C)C)OCC1C2=C(C=C(C=C2O[Si](C(C)C)(C(C)C)C(C)C)C=O)N3CC4C(C1(O3)OCOC)N4C(=O)OC > CC(C)[Si](C(C)C)(C(C)C)OC[C@H]1C2=C(C=C(C=C2O[Si](C(C)C)(C(C)C)C(C)C)C=O)N3C[C@H]4[C@@H]([C@@]1(O3)OCOC)N4C(=O)OC > 95.8 > 692.38881995 > 0 > 47 > 4 > 0 > 0 > 0 > 0 > 1 > -1 > 1 5 255 > 13 48 6 14 49 6 17 20 6 18 19 8 18 22 8 19 23 8 22 25 8 23 29 8 25 29 8 15 4 5 $$$$